Synthesis of 1-methyl-2-diphenylphosphino-3-(1'-isoquinolyl)indole; An easily racemised ligand giving insights into catalytic asymmetric allylation
The synthesis of the title compound is described, involving 2-lithiation and phosphinylation of the coupled heterocycle in the final step. Attempts to resolve the phosphine by previously described methods led to its immediate racemisation, also observed more slowly in the PdCl2 complex, for which th...
| المؤلفون الرئيسيون: | , , , , |
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| التنسيق: | Journal article |
| منشور في: |
1997
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