Synthesis of the pyrrolidinone core of KSM-2690 B.

Synthesis of the pyrrolidinone core of KSM-2690 B.

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[reaction: see text] The first synthesis of the pyrrolidinone core of the polyene beta-lactone antibiotic KSM-2690 B is described. An ammonia-free Birch reductive aldol reaction utilizing acetaldehyde is one of the key steps, together with a ruthenium-catalyzed alkene isomerization reaction.

书目详细资料
Main Authors:	Donohoe, T, Chiu, J, Thomas, R
格式:	Journal article
语言:	English
出版:	2007

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