A cyclic porphyrin trimer as a receptor for fullerenes.
A cyclic porphyrin trimer has been synthesized which has a high affinity for fullerenes. It forms 1:1 complexes with C(60) and C(70) with association constants of 2 x 10(6) and 2 x 10(8) M(-1), respectively, in toluene. Its affinities for C(86) and La@C(82) are too strong to measure by fluorescence...
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Bibliographic Details
Main Authors: |
Gil-Ramírez, G,
Karlen, S,
Shundo, A,
Porfyrakis, K,
Ito, Y,
Briggs, G,
Morton, J,
Anderson, H |
Format: | Journal article
|
Language: | English |
Published: |
2010
|