Mechanistic studies of the dehydrocoupling and dehydropolymerization of amine-boranes using a [Rh(Xantphos)]⁺ catalyst.
A detailed catalytic, stoichiometric, and mechanistic study on the dehydrocoupling of H3B·NMe2H and dehydropolymerization of H3B·NMeH2 using the [Rh(Xantphos)](+) fragment is reported. At 0.2 mol % catalyst loadings, dehydrocoupling produces dimeric [H2B-NMe2]2 and poly(methylaminoborane) (M(n) = 22...
| Main Authors: | , , , , , |
|---|---|
| Format: | Journal article |
| Language: | English |
| Published: |
American Chemical Society
2014
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Mechanistic studies of the dehydrocoupling and dehydropolymerization of amine-boranes using a [Rh(Xantphos)]⁺ catalyst
Published 2014
Journal article