Numerical simulation of the limiting current for the CE mechanism at a microdisc electrode
The finite difference method in conjunction with a conformal mapping technique is used to simulate the diffusion limiting current for three different CE mechanisms at a microdisc electrode. Working surfaces are presented for the variation of the limiting current with a normalised homogeneous kinetic...
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| Format: | Journal article |
| Language: | English |
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2008
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| _version_ | 1826283774273388544 |
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| author | Streeter, I Compton, R |
| author_facet | Streeter, I Compton, R |
| author_sort | Streeter, I |
| collection | OXFORD |
| description | The finite difference method in conjunction with a conformal mapping technique is used to simulate the diffusion limiting current for three different CE mechanisms at a microdisc electrode. Working surfaces are presented for the variation of the limiting current with a normalised homogeneous kinetic parameter and equilibrium constant. Empirical equations are given to describe the current when the homogeneous equilibrium position lies heavily in favour of the electroinactive species. © 2007 Elsevier B.V. All rights reserved. |
| first_indexed | 2024-03-07T01:03:57Z |
| format | Journal article |
| id | oxford-uuid:8aae2950-836a-42e0-9787-1a34079af962 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T01:03:57Z |
| publishDate | 2008 |
| record_format | dspace |
| spelling | oxford-uuid:8aae2950-836a-42e0-9787-1a34079af9622022-03-26T22:33:08ZNumerical simulation of the limiting current for the CE mechanism at a microdisc electrodeJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:8aae2950-836a-42e0-9787-1a34079af962EnglishSymplectic Elements at Oxford2008Streeter, ICompton, RThe finite difference method in conjunction with a conformal mapping technique is used to simulate the diffusion limiting current for three different CE mechanisms at a microdisc electrode. Working surfaces are presented for the variation of the limiting current with a normalised homogeneous kinetic parameter and equilibrium constant. Empirical equations are given to describe the current when the homogeneous equilibrium position lies heavily in favour of the electroinactive species. © 2007 Elsevier B.V. All rights reserved. |
| spellingShingle | Streeter, I Compton, R Numerical simulation of the limiting current for the CE mechanism at a microdisc electrode |
| title | Numerical simulation of the limiting current for the CE mechanism at a microdisc electrode |
| title_full | Numerical simulation of the limiting current for the CE mechanism at a microdisc electrode |
| title_fullStr | Numerical simulation of the limiting current for the CE mechanism at a microdisc electrode |
| title_full_unstemmed | Numerical simulation of the limiting current for the CE mechanism at a microdisc electrode |
| title_short | Numerical simulation of the limiting current for the CE mechanism at a microdisc electrode |
| title_sort | numerical simulation of the limiting current for the ce mechanism at a microdisc electrode |
| work_keys_str_mv | AT streeteri numericalsimulationofthelimitingcurrentforthecemechanismatamicrodiscelectrode AT comptonr numericalsimulationofthelimitingcurrentforthecemechanismatamicrodiscelectrode |