THE MICROWAVE-SPECTRUM OF THE OPEN-SHELL COMPLEX ARNO2
The 505←404, 404←303, 303←202 and 202←101 rotational transitions of the open-shell van der Waals complex ArNO2 have been observed using a Fourier-transform microwave spectrometer. The complex was produced by supersonic expansion of NO2 gas in argon. The spectrum showed fine, magnetic hyperfine and e...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
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1994
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| _version_ | 1797080719498936320 |
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| author | Low, R Whitham, C Varberg, T Howard, B |
| author_facet | Low, R Whitham, C Varberg, T Howard, B |
| author_sort | Low, R |
| collection | OXFORD |
| description | The 505←404, 404←303, 303←202 and 202←101 rotational transitions of the open-shell van der Waals complex ArNO2 have been observed using a Fourier-transform microwave spectrometer. The complex was produced by supersonic expansion of NO2 gas in argon. The spectrum showed fine, magnetic hyperfine and electric quadrupole structure. The data have been fitted to a semi- rigid Hamiltonian to determine the molecular parameters for the KitA=0 state. We discuss the implications of these derived parameters for the electronic and geometric stucture of the complex. © 1994. |
| first_indexed | 2024-03-07T01:04:10Z |
| format | Journal article |
| id | oxford-uuid:8ac03749-6ebf-4bc5-992e-8c69e1694af6 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T01:04:10Z |
| publishDate | 1994 |
| record_format | dspace |
| spelling | oxford-uuid:8ac03749-6ebf-4bc5-992e-8c69e1694af62022-03-26T22:33:32ZTHE MICROWAVE-SPECTRUM OF THE OPEN-SHELL COMPLEX ARNO2Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:8ac03749-6ebf-4bc5-992e-8c69e1694af6EnglishSymplectic Elements at Oxford1994Low, RWhitham, CVarberg, THoward, BThe 505←404, 404←303, 303←202 and 202←101 rotational transitions of the open-shell van der Waals complex ArNO2 have been observed using a Fourier-transform microwave spectrometer. The complex was produced by supersonic expansion of NO2 gas in argon. The spectrum showed fine, magnetic hyperfine and electric quadrupole structure. The data have been fitted to a semi- rigid Hamiltonian to determine the molecular parameters for the KitA=0 state. We discuss the implications of these derived parameters for the electronic and geometric stucture of the complex. © 1994. |
| spellingShingle | Low, R Whitham, C Varberg, T Howard, B THE MICROWAVE-SPECTRUM OF THE OPEN-SHELL COMPLEX ARNO2 |
| title | THE MICROWAVE-SPECTRUM OF THE OPEN-SHELL COMPLEX ARNO2 |
| title_full | THE MICROWAVE-SPECTRUM OF THE OPEN-SHELL COMPLEX ARNO2 |
| title_fullStr | THE MICROWAVE-SPECTRUM OF THE OPEN-SHELL COMPLEX ARNO2 |
| title_full_unstemmed | THE MICROWAVE-SPECTRUM OF THE OPEN-SHELL COMPLEX ARNO2 |
| title_short | THE MICROWAVE-SPECTRUM OF THE OPEN-SHELL COMPLEX ARNO2 |
| title_sort | microwave spectrum of the open shell complex arno2 |
| work_keys_str_mv | AT lowr themicrowavespectrumoftheopenshellcomplexarno2 AT whithamc themicrowavespectrumoftheopenshellcomplexarno2 AT varbergt themicrowavespectrumoftheopenshellcomplexarno2 AT howardb themicrowavespectrumoftheopenshellcomplexarno2 AT lowr microwavespectrumoftheopenshellcomplexarno2 AT whithamc microwavespectrumoftheopenshellcomplexarno2 AT varbergt microwavespectrumoftheopenshellcomplexarno2 AT howardb microwavespectrumoftheopenshellcomplexarno2 |