Crystal growth of A2V2O7 (A = Y, Er, and Dy) pyrochlores using high pressure
Single crystals of pyrochlore-type vanadates A2V 2O7 where A = Er, Y, and Dy have been successfully grown under high pressure and high temperature, using a multianvil technique. The temperature gradient method was applied for the crystal growth. The crystal structure of all three compounds has been...
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Format: | Journal article |
Language: | English |
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2008
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_version_ | 1797080741690998784 |
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author | Haghighirad, A Ritter, F Assmus, W |
author_facet | Haghighirad, A Ritter, F Assmus, W |
author_sort | Haghighirad, A |
collection | OXFORD |
description | Single crystals of pyrochlore-type vanadates A2V 2O7 where A = Er, Y, and Dy have been successfully grown under high pressure and high temperature, using a multianvil technique. The temperature gradient method was applied for the crystal growth. The crystal structure of all three compounds has been determined from the Rietveld analysis of X-ray powder diffraction (XRD) data and confirmed a cubic pyrochlore structure in space group Fd3̄m (No. 227). The unit cell parameters were a = 9.9924(1), 10.01438(8), and 10.0372(3) Å for Er2V 2O7, Y2V2O7, and Dy 2V2O7, respectively. Their compositions were investigated by energy dispersive X-ray analysis. A single crystal of Dy 2V2O7 was characterized by a single-crystal XRD method. © 2008 American Chemical Society. |
first_indexed | 2024-03-07T01:04:29Z |
format | Journal article |
id | oxford-uuid:8adabcdb-31ec-4680-8c57-edced77b1794 |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-07T01:04:29Z |
publishDate | 2008 |
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spelling | oxford-uuid:8adabcdb-31ec-4680-8c57-edced77b17942022-03-26T22:34:16ZCrystal growth of A2V2O7 (A = Y, Er, and Dy) pyrochlores using high pressureJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:8adabcdb-31ec-4680-8c57-edced77b1794EnglishSymplectic Elements at Oxford2008Haghighirad, ARitter, FAssmus, WSingle crystals of pyrochlore-type vanadates A2V 2O7 where A = Er, Y, and Dy have been successfully grown under high pressure and high temperature, using a multianvil technique. The temperature gradient method was applied for the crystal growth. The crystal structure of all three compounds has been determined from the Rietveld analysis of X-ray powder diffraction (XRD) data and confirmed a cubic pyrochlore structure in space group Fd3̄m (No. 227). The unit cell parameters were a = 9.9924(1), 10.01438(8), and 10.0372(3) Å for Er2V 2O7, Y2V2O7, and Dy 2V2O7, respectively. Their compositions were investigated by energy dispersive X-ray analysis. A single crystal of Dy 2V2O7 was characterized by a single-crystal XRD method. © 2008 American Chemical Society. |
spellingShingle | Haghighirad, A Ritter, F Assmus, W Crystal growth of A2V2O7 (A = Y, Er, and Dy) pyrochlores using high pressure |
title | Crystal growth of A2V2O7 (A = Y, Er, and Dy) pyrochlores using high pressure |
title_full | Crystal growth of A2V2O7 (A = Y, Er, and Dy) pyrochlores using high pressure |
title_fullStr | Crystal growth of A2V2O7 (A = Y, Er, and Dy) pyrochlores using high pressure |
title_full_unstemmed | Crystal growth of A2V2O7 (A = Y, Er, and Dy) pyrochlores using high pressure |
title_short | Crystal growth of A2V2O7 (A = Y, Er, and Dy) pyrochlores using high pressure |
title_sort | crystal growth of a2v2o7 a y er and dy pyrochlores using high pressure |
work_keys_str_mv | AT haghighirada crystalgrowthofa2v2o7ayeranddypyrochloresusinghighpressure AT ritterf crystalgrowthofa2v2o7ayeranddypyrochloresusinghighpressure AT assmusw crystalgrowthofa2v2o7ayeranddypyrochloresusinghighpressure |