Sulfonamide-Supported Aluminum Catalysts for the Ring-Opening Polymerization of rac-Lactide

The synthesis, structures, and ring-opening polymerization (ROP) capability of a wide range of sulfonamide-supported aluminum alkyl and alkoxide complexes are reported. The synthesis of the new protio-ligands PhCH2N(CH 2CH2NHSO2R)2 (R = ToI (15, H 2N2TsNph) or Me (16, H 2N2MsNph)) is described. Thes...

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Main Authors: Schwarz, A, Chu, Z, Mountford, P
格式: Journal article
語言:English
出版: 2010