Chemoselective debenzylation of N-benzyl tertiary amines with ceric ammonium nitrate

Treatment of a range of N-benzyl tertiary amines with aqueous eerie ammonium nitrate results in N-debenzylation to afford the corresponding secondary amine. Chemoselective mono-W-debenzylation of N-benzyl tertiary amines is shown to occur in the presence of N-benzyl amides, O-benzyl ethers, O-benzyl...

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Main Authors: Bull, S, Davies, S, Fenton, G, Mulvaney, A, Prasad, R, Smith, A
Format: Journal article
Language:English
Published: 2000
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author Bull, S
Davies, S
Fenton, G
Mulvaney, A
Prasad, R
Smith, A
author_facet Bull, S
Davies, S
Fenton, G
Mulvaney, A
Prasad, R
Smith, A
author_sort Bull, S
collection OXFORD
description Treatment of a range of N-benzyl tertiary amines with aqueous eerie ammonium nitrate results in N-debenzylation to afford the corresponding secondary amine. Chemoselective mono-W-debenzylation of N-benzyl tertiary amines is shown to occur in the presence of N-benzyl amides, O-benzyl ethers, O-benzyl esters, O-benzyl phenolates and 5-benzyl ethers. © The Royal Society of Chemistry 2000.
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spelling oxford-uuid:8bf2fb73-c2ef-4612-9087-732a33e93ee02022-03-26T22:41:29ZChemoselective debenzylation of N-benzyl tertiary amines with ceric ammonium nitrateJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:8bf2fb73-c2ef-4612-9087-732a33e93ee0EnglishSymplectic Elements at Oxford2000Bull, SDavies, SFenton, GMulvaney, APrasad, RSmith, ATreatment of a range of N-benzyl tertiary amines with aqueous eerie ammonium nitrate results in N-debenzylation to afford the corresponding secondary amine. Chemoselective mono-W-debenzylation of N-benzyl tertiary amines is shown to occur in the presence of N-benzyl amides, O-benzyl ethers, O-benzyl esters, O-benzyl phenolates and 5-benzyl ethers. © The Royal Society of Chemistry 2000.
spellingShingle Bull, S
Davies, S
Fenton, G
Mulvaney, A
Prasad, R
Smith, A
Chemoselective debenzylation of N-benzyl tertiary amines with ceric ammonium nitrate
title Chemoselective debenzylation of N-benzyl tertiary amines with ceric ammonium nitrate
title_full Chemoselective debenzylation of N-benzyl tertiary amines with ceric ammonium nitrate
title_fullStr Chemoselective debenzylation of N-benzyl tertiary amines with ceric ammonium nitrate
title_full_unstemmed Chemoselective debenzylation of N-benzyl tertiary amines with ceric ammonium nitrate
title_short Chemoselective debenzylation of N-benzyl tertiary amines with ceric ammonium nitrate
title_sort chemoselective debenzylation of n benzyl tertiary amines with ceric ammonium nitrate
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AT daviess chemoselectivedebenzylationofnbenzyltertiaryamineswithcericammoniumnitrate
AT fentong chemoselectivedebenzylationofnbenzyltertiaryamineswithcericammoniumnitrate
AT mulvaneya chemoselectivedebenzylationofnbenzyltertiaryamineswithcericammoniumnitrate
AT prasadr chemoselectivedebenzylationofnbenzyltertiaryamineswithcericammoniumnitrate
AT smitha chemoselectivedebenzylationofnbenzyltertiaryamineswithcericammoniumnitrate