Chemoselective debenzylation of N-benzyl tertiary amines with ceric ammonium nitrate
Treatment of a range of N-benzyl tertiary amines with aqueous eerie ammonium nitrate results in N-debenzylation to afford the corresponding secondary amine. Chemoselective mono-W-debenzylation of N-benzyl tertiary amines is shown to occur in the presence of N-benzyl amides, O-benzyl ethers, O-benzyl...
Main Authors: | , , , , , |
---|---|
Format: | Journal article |
Language: | English |
Published: |
2000
|
_version_ | 1826284037053874176 |
---|---|
author | Bull, S Davies, S Fenton, G Mulvaney, A Prasad, R Smith, A |
author_facet | Bull, S Davies, S Fenton, G Mulvaney, A Prasad, R Smith, A |
author_sort | Bull, S |
collection | OXFORD |
description | Treatment of a range of N-benzyl tertiary amines with aqueous eerie ammonium nitrate results in N-debenzylation to afford the corresponding secondary amine. Chemoselective mono-W-debenzylation of N-benzyl tertiary amines is shown to occur in the presence of N-benzyl amides, O-benzyl ethers, O-benzyl esters, O-benzyl phenolates and 5-benzyl ethers. © The Royal Society of Chemistry 2000. |
first_indexed | 2024-03-07T01:07:50Z |
format | Journal article |
id | oxford-uuid:8bf2fb73-c2ef-4612-9087-732a33e93ee0 |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-07T01:07:50Z |
publishDate | 2000 |
record_format | dspace |
spelling | oxford-uuid:8bf2fb73-c2ef-4612-9087-732a33e93ee02022-03-26T22:41:29ZChemoselective debenzylation of N-benzyl tertiary amines with ceric ammonium nitrateJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:8bf2fb73-c2ef-4612-9087-732a33e93ee0EnglishSymplectic Elements at Oxford2000Bull, SDavies, SFenton, GMulvaney, APrasad, RSmith, ATreatment of a range of N-benzyl tertiary amines with aqueous eerie ammonium nitrate results in N-debenzylation to afford the corresponding secondary amine. Chemoselective mono-W-debenzylation of N-benzyl tertiary amines is shown to occur in the presence of N-benzyl amides, O-benzyl ethers, O-benzyl esters, O-benzyl phenolates and 5-benzyl ethers. © The Royal Society of Chemistry 2000. |
spellingShingle | Bull, S Davies, S Fenton, G Mulvaney, A Prasad, R Smith, A Chemoselective debenzylation of N-benzyl tertiary amines with ceric ammonium nitrate |
title | Chemoselective debenzylation of N-benzyl tertiary amines with ceric ammonium nitrate |
title_full | Chemoselective debenzylation of N-benzyl tertiary amines with ceric ammonium nitrate |
title_fullStr | Chemoselective debenzylation of N-benzyl tertiary amines with ceric ammonium nitrate |
title_full_unstemmed | Chemoselective debenzylation of N-benzyl tertiary amines with ceric ammonium nitrate |
title_short | Chemoselective debenzylation of N-benzyl tertiary amines with ceric ammonium nitrate |
title_sort | chemoselective debenzylation of n benzyl tertiary amines with ceric ammonium nitrate |
work_keys_str_mv | AT bulls chemoselectivedebenzylationofnbenzyltertiaryamineswithcericammoniumnitrate AT daviess chemoselectivedebenzylationofnbenzyltertiaryamineswithcericammoniumnitrate AT fentong chemoselectivedebenzylationofnbenzyltertiaryamineswithcericammoniumnitrate AT mulvaneya chemoselectivedebenzylationofnbenzyltertiaryamineswithcericammoniumnitrate AT prasadr chemoselectivedebenzylationofnbenzyltertiaryamineswithcericammoniumnitrate AT smitha chemoselectivedebenzylationofnbenzyltertiaryamineswithcericammoniumnitrate |