Generation of cationic two-coordinate group-13 ligand systems by spontaneous halide ejection: remarkably nucleophile-resistant (dimethylamino)borylene complexes.
Spontaneous ejection of chloride from a three-coordinate boron Lewis acid can be effected by employing very electron rich metal substituents and leads to the formation of a sterically unprotected terminal (dimethylamino)borylene complex that has a short metal-boron bond and remarkable resistance to...
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Bibliographic Details
| Main Authors: |
Addy, D,
Pierce, G,
Vidovic, D,
Mallick, D,
Jemmis, E,
Goicoechea, J,
Aldridge, S |
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| Format: | Journal article
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| Language: | English |
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| Published: |
2010
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