Preparation of Sr7Mn4O13F2 by the topotactic reduction and subsequent fluorination of Sr7Mn4O15.

The topotactic reduction and subsequent fluorination of Sr7Mn4O15 yields a phase of composition Sr7Mn4O13F2. Characterization of this phase utilizing powder neutron diffraction and 19F NMR shows that the fluoride ions are located on a single anion site, the same crystallographic site that is vacant...

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Main Authors: Saratovsky, I, Lockett, M, Rees, N, Hayward, M
Format: Journal article
Language:English
Published: 2008
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author Saratovsky, I
Lockett, M
Rees, N
Hayward, M
author_facet Saratovsky, I
Lockett, M
Rees, N
Hayward, M
author_sort Saratovsky, I
collection OXFORD
description The topotactic reduction and subsequent fluorination of Sr7Mn4O15 yields a phase of composition Sr7Mn4O13F2. Characterization of this phase utilizing powder neutron diffraction and 19F NMR shows that the fluoride ions are located on a single anion site, the same crystallographic site that is vacant in the reduced intermediate Sr7Mn4O13.
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spelling oxford-uuid:8d305ca1-e40f-4360-89c2-e8a7224ecbc12022-03-26T22:49:38ZPreparation of Sr7Mn4O13F2 by the topotactic reduction and subsequent fluorination of Sr7Mn4O15.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:8d305ca1-e40f-4360-89c2-e8a7224ecbc1EnglishSymplectic Elements at Oxford2008Saratovsky, ILockett, MRees, NHayward, MThe topotactic reduction and subsequent fluorination of Sr7Mn4O15 yields a phase of composition Sr7Mn4O13F2. Characterization of this phase utilizing powder neutron diffraction and 19F NMR shows that the fluoride ions are located on a single anion site, the same crystallographic site that is vacant in the reduced intermediate Sr7Mn4O13.
spellingShingle Saratovsky, I
Lockett, M
Rees, N
Hayward, M
Preparation of Sr7Mn4O13F2 by the topotactic reduction and subsequent fluorination of Sr7Mn4O15.
title Preparation of Sr7Mn4O13F2 by the topotactic reduction and subsequent fluorination of Sr7Mn4O15.
title_full Preparation of Sr7Mn4O13F2 by the topotactic reduction and subsequent fluorination of Sr7Mn4O15.
title_fullStr Preparation of Sr7Mn4O13F2 by the topotactic reduction and subsequent fluorination of Sr7Mn4O15.
title_full_unstemmed Preparation of Sr7Mn4O13F2 by the topotactic reduction and subsequent fluorination of Sr7Mn4O15.
title_short Preparation of Sr7Mn4O13F2 by the topotactic reduction and subsequent fluorination of Sr7Mn4O15.
title_sort preparation of sr7mn4o13f2 by the topotactic reduction and subsequent fluorination of sr7mn4o15
work_keys_str_mv AT saratovskyi preparationofsr7mn4o13f2bythetopotacticreductionandsubsequentfluorinationofsr7mn4o15
AT lockettm preparationofsr7mn4o13f2bythetopotacticreductionandsubsequentfluorinationofsr7mn4o15
AT reesn preparationofsr7mn4o13f2bythetopotacticreductionandsubsequentfluorinationofsr7mn4o15
AT haywardm preparationofsr7mn4o13f2bythetopotacticreductionandsubsequentfluorinationofsr7mn4o15