Preparation of Sr7Mn4O13F2 by the topotactic reduction and subsequent fluorination of Sr7Mn4O15.
The topotactic reduction and subsequent fluorination of Sr7Mn4O15 yields a phase of composition Sr7Mn4O13F2. Characterization of this phase utilizing powder neutron diffraction and 19F NMR shows that the fluoride ions are located on a single anion site, the same crystallographic site that is vacant...
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Format: | Journal article |
Language: | English |
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2008
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author | Saratovsky, I Lockett, M Rees, N Hayward, M |
author_facet | Saratovsky, I Lockett, M Rees, N Hayward, M |
author_sort | Saratovsky, I |
collection | OXFORD |
description | The topotactic reduction and subsequent fluorination of Sr7Mn4O15 yields a phase of composition Sr7Mn4O13F2. Characterization of this phase utilizing powder neutron diffraction and 19F NMR shows that the fluoride ions are located on a single anion site, the same crystallographic site that is vacant in the reduced intermediate Sr7Mn4O13. |
first_indexed | 2024-03-07T01:11:35Z |
format | Journal article |
id | oxford-uuid:8d305ca1-e40f-4360-89c2-e8a7224ecbc1 |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-07T01:11:35Z |
publishDate | 2008 |
record_format | dspace |
spelling | oxford-uuid:8d305ca1-e40f-4360-89c2-e8a7224ecbc12022-03-26T22:49:38ZPreparation of Sr7Mn4O13F2 by the topotactic reduction and subsequent fluorination of Sr7Mn4O15.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:8d305ca1-e40f-4360-89c2-e8a7224ecbc1EnglishSymplectic Elements at Oxford2008Saratovsky, ILockett, MRees, NHayward, MThe topotactic reduction and subsequent fluorination of Sr7Mn4O15 yields a phase of composition Sr7Mn4O13F2. Characterization of this phase utilizing powder neutron diffraction and 19F NMR shows that the fluoride ions are located on a single anion site, the same crystallographic site that is vacant in the reduced intermediate Sr7Mn4O13. |
spellingShingle | Saratovsky, I Lockett, M Rees, N Hayward, M Preparation of Sr7Mn4O13F2 by the topotactic reduction and subsequent fluorination of Sr7Mn4O15. |
title | Preparation of Sr7Mn4O13F2 by the topotactic reduction and subsequent fluorination of Sr7Mn4O15. |
title_full | Preparation of Sr7Mn4O13F2 by the topotactic reduction and subsequent fluorination of Sr7Mn4O15. |
title_fullStr | Preparation of Sr7Mn4O13F2 by the topotactic reduction and subsequent fluorination of Sr7Mn4O15. |
title_full_unstemmed | Preparation of Sr7Mn4O13F2 by the topotactic reduction and subsequent fluorination of Sr7Mn4O15. |
title_short | Preparation of Sr7Mn4O13F2 by the topotactic reduction and subsequent fluorination of Sr7Mn4O15. |
title_sort | preparation of sr7mn4o13f2 by the topotactic reduction and subsequent fluorination of sr7mn4o15 |
work_keys_str_mv | AT saratovskyi preparationofsr7mn4o13f2bythetopotacticreductionandsubsequentfluorinationofsr7mn4o15 AT lockettm preparationofsr7mn4o13f2bythetopotacticreductionandsubsequentfluorinationofsr7mn4o15 AT reesn preparationofsr7mn4o13f2bythetopotacticreductionandsubsequentfluorinationofsr7mn4o15 AT haywardm preparationofsr7mn4o13f2bythetopotacticreductionandsubsequentfluorinationofsr7mn4o15 |