Single-wall-carbon-nanotube/single-carbon-chain molecular junctions

Stable junctions between a single carbon chain and two single-wall carbon nanotubes were produced via coalescence of functionalized fullerenes filled into a single-wall carbon nanotube and directly imaged by in situ transmission electron microscopy. First principles quantum chemical calculations sup...

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Main Authors: Boerrnert, F, Boerrnert, C, Gorantla, S, Liu, X, Bachmatiuk, A, Joswig, J, Wagner, F, Schaeffel, F, Warner, J, Schoenfelder, R, Rellinghaus, B, Gemming, T, Thomas, J, Knupfer, M, Buechner, B, Ruemmeli, M
Format: Journal article
Language:English
Published: 2010
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author Boerrnert, F
Boerrnert, C
Gorantla, S
Liu, X
Bachmatiuk, A
Joswig, J
Wagner, F
Schaeffel, F
Warner, J
Schoenfelder, R
Rellinghaus, B
Gemming, T
Thomas, J
Knupfer, M
Buechner, B
Ruemmeli, M
author_facet Boerrnert, F
Boerrnert, C
Gorantla, S
Liu, X
Bachmatiuk, A
Joswig, J
Wagner, F
Schaeffel, F
Warner, J
Schoenfelder, R
Rellinghaus, B
Gemming, T
Thomas, J
Knupfer, M
Buechner, B
Ruemmeli, M
author_sort Boerrnert, F
collection OXFORD
description Stable junctions between a single carbon chain and two single-wall carbon nanotubes were produced via coalescence of functionalized fullerenes filled into a single-wall carbon nanotube and directly imaged by in situ transmission electron microscopy. First principles quantum chemical calculations support the observed stability of such molecular junctions. They also show that short carbon chains bound to other carbon structures are cumulenes and stable semiconductors due to Peierls-like distortion. Junctions like this can be regarded as archetypical building blocks for all-carbon molecular electronics. © 2010 The American Physical Society.
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spelling oxford-uuid:8e4b49ae-349e-4d8e-8e53-3ced1c3536052022-03-26T22:56:41ZSingle-wall-carbon-nanotube/single-carbon-chain molecular junctionsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:8e4b49ae-349e-4d8e-8e53-3ced1c353605EnglishSymplectic Elements at Oxford2010Boerrnert, FBoerrnert, CGorantla, SLiu, XBachmatiuk, AJoswig, JWagner, FSchaeffel, FWarner, JSchoenfelder, RRellinghaus, BGemming, TThomas, JKnupfer, MBuechner, BRuemmeli, MStable junctions between a single carbon chain and two single-wall carbon nanotubes were produced via coalescence of functionalized fullerenes filled into a single-wall carbon nanotube and directly imaged by in situ transmission electron microscopy. First principles quantum chemical calculations support the observed stability of such molecular junctions. They also show that short carbon chains bound to other carbon structures are cumulenes and stable semiconductors due to Peierls-like distortion. Junctions like this can be regarded as archetypical building blocks for all-carbon molecular electronics. © 2010 The American Physical Society.
spellingShingle Boerrnert, F
Boerrnert, C
Gorantla, S
Liu, X
Bachmatiuk, A
Joswig, J
Wagner, F
Schaeffel, F
Warner, J
Schoenfelder, R
Rellinghaus, B
Gemming, T
Thomas, J
Knupfer, M
Buechner, B
Ruemmeli, M
Single-wall-carbon-nanotube/single-carbon-chain molecular junctions
title Single-wall-carbon-nanotube/single-carbon-chain molecular junctions
title_full Single-wall-carbon-nanotube/single-carbon-chain molecular junctions
title_fullStr Single-wall-carbon-nanotube/single-carbon-chain molecular junctions
title_full_unstemmed Single-wall-carbon-nanotube/single-carbon-chain molecular junctions
title_short Single-wall-carbon-nanotube/single-carbon-chain molecular junctions
title_sort single wall carbon nanotube single carbon chain molecular junctions
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