Single-wall-carbon-nanotube/single-carbon-chain molecular junctions
Stable junctions between a single carbon chain and two single-wall carbon nanotubes were produced via coalescence of functionalized fullerenes filled into a single-wall carbon nanotube and directly imaged by in situ transmission electron microscopy. First principles quantum chemical calculations sup...
Main Authors: | , , , , , , , , , , , , , , , |
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Format: | Journal article |
Language: | English |
Published: |
2010
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_version_ | 1826284503870472192 |
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author | Boerrnert, F Boerrnert, C Gorantla, S Liu, X Bachmatiuk, A Joswig, J Wagner, F Schaeffel, F Warner, J Schoenfelder, R Rellinghaus, B Gemming, T Thomas, J Knupfer, M Buechner, B Ruemmeli, M |
author_facet | Boerrnert, F Boerrnert, C Gorantla, S Liu, X Bachmatiuk, A Joswig, J Wagner, F Schaeffel, F Warner, J Schoenfelder, R Rellinghaus, B Gemming, T Thomas, J Knupfer, M Buechner, B Ruemmeli, M |
author_sort | Boerrnert, F |
collection | OXFORD |
description | Stable junctions between a single carbon chain and two single-wall carbon nanotubes were produced via coalescence of functionalized fullerenes filled into a single-wall carbon nanotube and directly imaged by in situ transmission electron microscopy. First principles quantum chemical calculations support the observed stability of such molecular junctions. They also show that short carbon chains bound to other carbon structures are cumulenes and stable semiconductors due to Peierls-like distortion. Junctions like this can be regarded as archetypical building blocks for all-carbon molecular electronics. © 2010 The American Physical Society. |
first_indexed | 2024-03-07T01:14:49Z |
format | Journal article |
id | oxford-uuid:8e4b49ae-349e-4d8e-8e53-3ced1c353605 |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-07T01:14:49Z |
publishDate | 2010 |
record_format | dspace |
spelling | oxford-uuid:8e4b49ae-349e-4d8e-8e53-3ced1c3536052022-03-26T22:56:41ZSingle-wall-carbon-nanotube/single-carbon-chain molecular junctionsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:8e4b49ae-349e-4d8e-8e53-3ced1c353605EnglishSymplectic Elements at Oxford2010Boerrnert, FBoerrnert, CGorantla, SLiu, XBachmatiuk, AJoswig, JWagner, FSchaeffel, FWarner, JSchoenfelder, RRellinghaus, BGemming, TThomas, JKnupfer, MBuechner, BRuemmeli, MStable junctions between a single carbon chain and two single-wall carbon nanotubes were produced via coalescence of functionalized fullerenes filled into a single-wall carbon nanotube and directly imaged by in situ transmission electron microscopy. First principles quantum chemical calculations support the observed stability of such molecular junctions. They also show that short carbon chains bound to other carbon structures are cumulenes and stable semiconductors due to Peierls-like distortion. Junctions like this can be regarded as archetypical building blocks for all-carbon molecular electronics. © 2010 The American Physical Society. |
spellingShingle | Boerrnert, F Boerrnert, C Gorantla, S Liu, X Bachmatiuk, A Joswig, J Wagner, F Schaeffel, F Warner, J Schoenfelder, R Rellinghaus, B Gemming, T Thomas, J Knupfer, M Buechner, B Ruemmeli, M Single-wall-carbon-nanotube/single-carbon-chain molecular junctions |
title | Single-wall-carbon-nanotube/single-carbon-chain molecular junctions |
title_full | Single-wall-carbon-nanotube/single-carbon-chain molecular junctions |
title_fullStr | Single-wall-carbon-nanotube/single-carbon-chain molecular junctions |
title_full_unstemmed | Single-wall-carbon-nanotube/single-carbon-chain molecular junctions |
title_short | Single-wall-carbon-nanotube/single-carbon-chain molecular junctions |
title_sort | single wall carbon nanotube single carbon chain molecular junctions |
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