TERTIARY PHOSPHINE ADDUCTS OF [W2(MU-O2CBU(T))4] - CRYSTAL-STRUCTURE OF [W2(MU-O2CBU(T))3(O2CBU(T)) (PME2PH)2]
Treatment of the quadruply bonded ditungsten complex [W2(μ-O2CBut)4] with phosphines PMeRR′ (R = R′ = Me or Ph; R = Me, R′ = Ph) affords bis(adducts) which have the general formula W2(O2CBut)4·2PMeRR′. Each adduct possesses a different arrangement of the PMeRR′ and O2CBut ligands. The complex [W2(μ-...
| Main Authors: | , |
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| Format: | Journal article |
| Language: | English |
| Published: |
1993
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