KINETIC RESOLUTION OF THE CHIRAL IRON ACETYL [FE(MU(5)-C5H5)(CO)(PPH3)COME]
The chiral discrimination displayed between the enolate derived from (RS)-[Fe(η5-C5H5)(CO)(PPh3)COMe] and (1R)-(+)-camphor furnishes a practical route to homochiral (R)-[Fe(η5-C5H5)(CO)(PPh3)COMe] via a kinetic resolution protocol, while a retro-aldol reaction of the diastereoisomerically pure aldol...
| Autori principali: | , , , , , |
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| Natura: | Journal article |
| Lingua: | English |
| Pubblicazione: |
1993
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| _version_ | 1826284587434639360 |
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| author | Casegreen, S Costello, J Davies, S Heaton, N Hedgecock, C Prime, J |
| author_facet | Casegreen, S Costello, J Davies, S Heaton, N Hedgecock, C Prime, J |
| author_sort | Casegreen, S |
| collection | OXFORD |
| description | The chiral discrimination displayed between the enolate derived from (RS)-[Fe(η5-C5H5)(CO)(PPh3)COMe] and (1R)-(+)-camphor furnishes a practical route to homochiral (R)-[Fe(η5-C5H5)(CO)(PPh3)COMe] via a kinetic resolution protocol, while a retro-aldol reaction of the diastereoisomerically pure aldol addition product of this kinetic resolution sequence provides a complementary route to the opposite enantiomer (S)-[Fe(η5-C5H5)(CO)(PPh3)COMe]. |
| first_indexed | 2024-03-07T01:16:05Z |
| format | Journal article |
| id | oxford-uuid:8ebb10f7-78a0-4ba9-813d-fa2f54032ffa |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T01:16:05Z |
| publishDate | 1993 |
| record_format | dspace |
| spelling | oxford-uuid:8ebb10f7-78a0-4ba9-813d-fa2f54032ffa2022-03-26T22:59:38ZKINETIC RESOLUTION OF THE CHIRAL IRON ACETYL [FE(MU(5)-C5H5)(CO)(PPH3)COME]Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:8ebb10f7-78a0-4ba9-813d-fa2f54032ffaEnglishSymplectic Elements at Oxford1993Casegreen, SCostello, JDavies, SHeaton, NHedgecock, CPrime, JThe chiral discrimination displayed between the enolate derived from (RS)-[Fe(η5-C5H5)(CO)(PPh3)COMe] and (1R)-(+)-camphor furnishes a practical route to homochiral (R)-[Fe(η5-C5H5)(CO)(PPh3)COMe] via a kinetic resolution protocol, while a retro-aldol reaction of the diastereoisomerically pure aldol addition product of this kinetic resolution sequence provides a complementary route to the opposite enantiomer (S)-[Fe(η5-C5H5)(CO)(PPh3)COMe]. |
| spellingShingle | Casegreen, S Costello, J Davies, S Heaton, N Hedgecock, C Prime, J KINETIC RESOLUTION OF THE CHIRAL IRON ACETYL [FE(MU(5)-C5H5)(CO)(PPH3)COME] |
| title | KINETIC RESOLUTION OF THE CHIRAL IRON ACETYL [FE(MU(5)-C5H5)(CO)(PPH3)COME] |
| title_full | KINETIC RESOLUTION OF THE CHIRAL IRON ACETYL [FE(MU(5)-C5H5)(CO)(PPH3)COME] |
| title_fullStr | KINETIC RESOLUTION OF THE CHIRAL IRON ACETYL [FE(MU(5)-C5H5)(CO)(PPH3)COME] |
| title_full_unstemmed | KINETIC RESOLUTION OF THE CHIRAL IRON ACETYL [FE(MU(5)-C5H5)(CO)(PPH3)COME] |
| title_short | KINETIC RESOLUTION OF THE CHIRAL IRON ACETYL [FE(MU(5)-C5H5)(CO)(PPH3)COME] |
| title_sort | kinetic resolution of the chiral iron acetyl fe mu 5 c5h5 co pph3 come |
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