KINETIC RESOLUTION OF THE CHIRAL IRON ACETYL [FE(MU(5)-C5H5)(CO)(PPH3)COME]

The chiral discrimination displayed between the enolate derived from (RS)-[Fe(η5-C5H5)(CO)(PPh3)COMe] and (1R)-(+)-camphor furnishes a practical route to homochiral (R)-[Fe(η5-C5H5)(CO)(PPh3)COMe] via a kinetic resolution protocol, while a retro-aldol reaction of the diastereoisomerically pure aldol...

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Bibliografiset tiedot
Päätekijät: Casegreen, S, Costello, J, Davies, S, Heaton, N, Hedgecock, C, Prime, J
Aineistotyyppi: Journal article
Kieli:English
Julkaistu: 1993