Detection of hydrogen sulfide above the clouds in Uranus’s atmosphere

Visible-to-near-infrared observations indicate that the cloud top of the main cloud deck on Uranus lies at a pressure level of between 1.2 bar and 3 bar. However, its composition has never been unambiguously identified, although it is widely assumed to be composed primarily of either ammonia or hydr...

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Main Authors: Irwin, P, Toledo Carrasco, D, Garland, R, Teanby, N, Fletcher, L, Orton, G, Bezard, B
Format: Journal article
Published: Nature Publishing Group 2018
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author Irwin, P
Toledo Carrasco, D
Garland, R
Teanby, N
Fletcher, L
Orton, G
Bezard, B
author_facet Irwin, P
Toledo Carrasco, D
Garland, R
Teanby, N
Fletcher, L
Orton, G
Bezard, B
author_sort Irwin, P
collection OXFORD
description Visible-to-near-infrared observations indicate that the cloud top of the main cloud deck on Uranus lies at a pressure level of between 1.2 bar and 3 bar. However, its composition has never been unambiguously identified, although it is widely assumed to be composed primarily of either ammonia or hydrogen sulfide (H2S) ice. Here, we present evidence of a clear detection of gaseous H2S above this cloud deck in the wavelength region 1.57–1.59 μm with a mole fraction of 0.4–0.8 ppm at the cloud top. Its detection constrains the deep bulk sulfur/nitrogen abundance to exceed unity (>4.4–5.0 times the solar value) in Uranus’s bulk atmosphere, and places a lower limit on the mole fraction of H2S below the observed cloud of (1.0−2.5)×10−5. The detection of gaseous H2S at these pressure levels adds to the weight of evidence that the principal constituent of 1.2–3-bar cloud is likely to be H2S ice.
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spelling oxford-uuid:8ef4459a-29ec-4420-87af-e149c4f35c732022-03-26T23:01:08ZDetection of hydrogen sulfide above the clouds in Uranus’s atmosphereJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:8ef4459a-29ec-4420-87af-e149c4f35c73Symplectic Elements at OxfordNature Publishing Group2018Irwin, PToledo Carrasco, DGarland, RTeanby, NFletcher, LOrton, GBezard, BVisible-to-near-infrared observations indicate that the cloud top of the main cloud deck on Uranus lies at a pressure level of between 1.2 bar and 3 bar. However, its composition has never been unambiguously identified, although it is widely assumed to be composed primarily of either ammonia or hydrogen sulfide (H2S) ice. Here, we present evidence of a clear detection of gaseous H2S above this cloud deck in the wavelength region 1.57–1.59 μm with a mole fraction of 0.4–0.8 ppm at the cloud top. Its detection constrains the deep bulk sulfur/nitrogen abundance to exceed unity (>4.4–5.0 times the solar value) in Uranus’s bulk atmosphere, and places a lower limit on the mole fraction of H2S below the observed cloud of (1.0−2.5)×10−5. The detection of gaseous H2S at these pressure levels adds to the weight of evidence that the principal constituent of 1.2–3-bar cloud is likely to be H2S ice.
spellingShingle Irwin, P
Toledo Carrasco, D
Garland, R
Teanby, N
Fletcher, L
Orton, G
Bezard, B
Detection of hydrogen sulfide above the clouds in Uranus’s atmosphere
title Detection of hydrogen sulfide above the clouds in Uranus’s atmosphere
title_full Detection of hydrogen sulfide above the clouds in Uranus’s atmosphere
title_fullStr Detection of hydrogen sulfide above the clouds in Uranus’s atmosphere
title_full_unstemmed Detection of hydrogen sulfide above the clouds in Uranus’s atmosphere
title_short Detection of hydrogen sulfide above the clouds in Uranus’s atmosphere
title_sort detection of hydrogen sulfide above the clouds in uranus s atmosphere
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