A stereoselective total synthesis of (±)-tormesol

A general strategy for the synthesis of both trans/syn- and trans/anti-sphenolobane diterpenes has been developed, which utilizes an intramolecular ester enolate alkylation (IEEA) as a key step. A stereoselective total synthesis of (±)-tormesol (1), an unusual trans/syn-sphenolobane diterpene, was a...

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Main Authors: Kim, H, Bae, H, Kim, S, Kim, D, Lee, D, Paton, R
格式: Journal article
语言:English
出版: Elsevier 2011