Heterogeneous and homogeneous EC and ECE processes at channel electrodes: Analytical wave shape theory
Analytical theory is developed for EC and ECE processes, both homogeneous and heterogeneous, occurring at channel electrodes for the case where the electron transfer is electrochemically reversible. In particular the variation of the half-wave potential with solution flow rate and/or cell geometry i...
| Váldodahkkit: | , |
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| Materiálatiipa: | Journal article |
| Giella: | English |
| Almmustuhtton: |
1999
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| _version_ | 1826284762840432640 |
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| author | Morland, P Compton, R |
| author_facet | Morland, P Compton, R |
| author_sort | Morland, P |
| collection | OXFORD |
| description | Analytical theory is developed for EC and ECE processes, both homogeneous and heterogeneous, occurring at channel electrodes for the case where the electron transfer is electrochemically reversible. In particular the variation of the half-wave potential with solution flow rate and/or cell geometry is shown to provide a sensitive indication of electrode reaction mechanism type. Simple expressions are presented which allow the ready mechanistic interpretation of experimental data and the deduction of corresponding rate constants. |
| first_indexed | 2024-03-07T01:18:43Z |
| format | Journal article |
| id | oxford-uuid:8f988a2f-2e4f-4039-becc-87e97c456e3d |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T01:18:43Z |
| publishDate | 1999 |
| record_format | dspace |
| spelling | oxford-uuid:8f988a2f-2e4f-4039-becc-87e97c456e3d2022-03-26T23:05:32ZHeterogeneous and homogeneous EC and ECE processes at channel electrodes: Analytical wave shape theoryJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:8f988a2f-2e4f-4039-becc-87e97c456e3dEnglishSymplectic Elements at Oxford1999Morland, PCompton, RAnalytical theory is developed for EC and ECE processes, both homogeneous and heterogeneous, occurring at channel electrodes for the case where the electron transfer is electrochemically reversible. In particular the variation of the half-wave potential with solution flow rate and/or cell geometry is shown to provide a sensitive indication of electrode reaction mechanism type. Simple expressions are presented which allow the ready mechanistic interpretation of experimental data and the deduction of corresponding rate constants. |
| spellingShingle | Morland, P Compton, R Heterogeneous and homogeneous EC and ECE processes at channel electrodes: Analytical wave shape theory |
| title | Heterogeneous and homogeneous EC and ECE processes at channel electrodes: Analytical wave shape theory |
| title_full | Heterogeneous and homogeneous EC and ECE processes at channel electrodes: Analytical wave shape theory |
| title_fullStr | Heterogeneous and homogeneous EC and ECE processes at channel electrodes: Analytical wave shape theory |
| title_full_unstemmed | Heterogeneous and homogeneous EC and ECE processes at channel electrodes: Analytical wave shape theory |
| title_short | Heterogeneous and homogeneous EC and ECE processes at channel electrodes: Analytical wave shape theory |
| title_sort | heterogeneous and homogeneous ec and ece processes at channel electrodes analytical wave shape theory |
| work_keys_str_mv | AT morlandp heterogeneousandhomogeneousecandeceprocessesatchannelelectrodesanalyticalwaveshapetheory AT comptonr heterogeneousandhomogeneousecandeceprocessesatchannelelectrodesanalyticalwaveshapetheory |