The [Rh(Xantphos)]+ catalyzed hydroboration of diphenylacetylene using trimethylamine-borane
The rhodium(I) complex [Rh(κ3-P,O,P-Xantphos)(η2-PhC≡CPh)][BArF4] (ArF = 3,5-(CF3)2C6H4) is an effective catalyst for the cis-selective hydroboration of the alkyne diphenylacetylene using the amine-borane H3B·NMe3. Detailed mechanistic studies, that include initial rate measurements, full simulation...
| Main Authors: | , , , |
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| Format: | Journal article |
| Published: |
Elsevier
2019
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