Toward cationic gallane- and indanediyl complexes: Synthetic approaches to three-coordinate halogallyl and -indyl precursors
Transition metal complexes containing ligands featuring three-coordinate, halide-functionalized gallium or indium donors represent key precursors to unsaturated cationic species of the type [LnM(EX)]+ via halide abstraction chemistry. Two routes to these three-coordinate systems have been demonstrat...
Main Authors: | Bunn, N, Aldridge, S, Kays, D, Coombs, N, Day, J, Ooi, L, Coles, S, Hursthouse, M |
---|---|
Format: | Journal article |
Language: | English |
Published: |
2005
|
Similar Items
-
Linking of main group metals via bridging halide ligands: Structures of the bromo-indanediyl dimer [{(eta(5)-C5H5)Fe(CO)(2)}(2)InBr](2) and the related lithium bromide adduct [(eta(5)-C5H5)Fe(CO)(2)](2)In(mu-Br)(2)Li(OEt2)(2)
by: Coombs, N, et al.
Published: (2007) -
Synthetic and reaction chemistry of heteroatom stabilized boryl and cationic borylene complexes.
by: Kays Née Coombs, D, et al.
Published: (2006) -
Halide abstraction as a route to cationic transition-metal complexes containing two-coordinate gallium and indium ligand systems
by: Bunn, N, et al.
Published: (2005) -
Substitution, abstraction and addition chemistry of low-coordinate gallium and indium ligand systems
by: Coombs, N, et al.
Published: (2006) -
Cationic terminal borylene complexes: a synthetic and mechanistic investigation of M=B metathesis chemistry.
by: Kays, D, et al.
Published: (2005)