Rationalizing the diverse reactivity of [1.1.1]propellane through sigma-pi-delocalization

Rationalizing the diverse reactivity of [1.1.1]propellane through sigma-pi-delocalization

[1.1.1]Propellane is the ubiquitous precursor to bicyclo[1.1.1]pentanes (BCPs), motifs of high value in pharmaceutical and materials research. The classical Lewis representation of this molecule places an inter-bridgehead C–C bond along its central axis; ‘strain relief’-driven cleavage of this bond...

Podrobná bibliografie
Hlavní autoři:	Sterling, AJ, Dürr, A, Smith, R, Anderson, EA, Duarte, F
Médium:	Journal article
Jazyk:	English
Vydáno:	Royal Society of Chemistry 2020

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