An insight into PWR primary water SCC mechanisms by comparing surface and crack oxidation

Oxidation and stress corrosion cracking (SCC) of 316L stainless steel were studied in simulated pressurized water reactor primary water. Surface, crack flank, and crack tip oxides were analyzed and compared by high-resolution characterization, including oxidation state mapping. All oxides were found...

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Auteurs principaux: Shen, Z, Du, D, Zhang, L, Lozano-Perez, S
Format: Journal article
Langue:English
Publié: Elsevier 2018
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author Shen, Z
Du, D
Zhang, L
Lozano-Perez, S
author_facet Shen, Z
Du, D
Zhang, L
Lozano-Perez, S
author_sort Shen, Z
collection OXFORD
description Oxidation and stress corrosion cracking (SCC) of 316L stainless steel were studied in simulated pressurized water reactor primary water. Surface, crack flank, and crack tip oxides were analyzed and compared by high-resolution characterization, including oxidation state mapping. All oxides were found to have a triplex structure, although of different dimensions and composition, revealing the effects of local water chemistry and applied stress. The higher oxidation rate at the crack tip could be explained due to the existence of a higher dislocation density, higher level of stress and cation unavailability from the environment. The implications to SCC mechanisms are discussed.
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spelling oxford-uuid:927b6241-5f15-42e4-b4a9-1d999409f86c2023-03-17T10:53:35ZAn insight into PWR primary water SCC mechanisms by comparing surface and crack oxidationJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:927b6241-5f15-42e4-b4a9-1d999409f86cEnglishSymplectic Elements at OxfordElsevier2018Shen, ZDu, DZhang, LLozano-Perez, SOxidation and stress corrosion cracking (SCC) of 316L stainless steel were studied in simulated pressurized water reactor primary water. Surface, crack flank, and crack tip oxides were analyzed and compared by high-resolution characterization, including oxidation state mapping. All oxides were found to have a triplex structure, although of different dimensions and composition, revealing the effects of local water chemistry and applied stress. The higher oxidation rate at the crack tip could be explained due to the existence of a higher dislocation density, higher level of stress and cation unavailability from the environment. The implications to SCC mechanisms are discussed.
spellingShingle Shen, Z
Du, D
Zhang, L
Lozano-Perez, S
An insight into PWR primary water SCC mechanisms by comparing surface and crack oxidation
title An insight into PWR primary water SCC mechanisms by comparing surface and crack oxidation
title_full An insight into PWR primary water SCC mechanisms by comparing surface and crack oxidation
title_fullStr An insight into PWR primary water SCC mechanisms by comparing surface and crack oxidation
title_full_unstemmed An insight into PWR primary water SCC mechanisms by comparing surface and crack oxidation
title_short An insight into PWR primary water SCC mechanisms by comparing surface and crack oxidation
title_sort insight into pwr primary water scc mechanisms by comparing surface and crack oxidation
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