Total synthesis of (+)-cis-sylvaticin: double oxidative cyclization reactions catalyzed by osmium.
The double oxidative cyclization of dienes is a viable procedure for making complex natural products containing cis-THF units. A double deprotection/double oxidative cyclization strategy using catalytic osmium tetroxide was used to construct the bisheterocyclic core of cis-sylvaticin and ultimately...
Main Authors: | , , , |
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Format: | Journal article |
Language: | English |
Published: |
2006
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