Total synthesis of (+)-cis-sylvaticin: double oxidative cyclization reactions catalyzed by osmium.
The double oxidative cyclization of dienes is a viable procedure for making complex natural products containing cis-THF units. A double deprotection/double oxidative cyclization strategy using catalytic osmium tetroxide was used to construct the bisheterocyclic core of cis-sylvaticin and ultimately...
Main Authors: | Donohoe, T, Harris, R, Burrows, J, Parker, J |
---|---|
Format: | Journal article |
Language: | English |
Published: |
2006
|
Similar Items
-
Concise syntheses of the natural products (+)-sylvaticin and (+)-cis-sylvaticin.
by: Donohoe, T, et al.
Published: (2009) -
New modes for the osmium-catalyzed oxidative cyclization.
by: Donohoe, T, et al.
Published: (2010) -
Osmium-catalyzed oxidative cyclization of dienes and their derivatives.
by: Pilgrim, B, et al.
Published: (2013) -
Pyridine-N-oxide as a mild reoxidant which transforms osmium-catalyzed oxidative cyclization.
by: Donohoe, T, et al.
Published: (2008) -
Stereoselective synthesis of pyrrolidines: catalytic oxidative cyclizations mediated by osmium.
by: Donohoe, T, et al.
Published: (2006)