Total synthesis of (+)-cis-sylvaticin: double oxidative cyclization reactions catalyzed by osmium.

The double oxidative cyclization of dienes is a viable procedure for making complex natural products containing cis-THF units. A double deprotection/double oxidative cyclization strategy using catalytic osmium tetroxide was used to construct the bisheterocyclic core of cis-sylvaticin and ultimately...

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Hlavní autoři: Donohoe, T, Harris, R, Burrows, J, Parker, J
Médium: Journal article
Jazyk:English
Vydáno: 2006