DECAMETHYLOSMOCENE AND DECAMETHYLOSMOCENIUM - UV AND X-RAY PHOTOELECTRON, MAGNETIC, AND ELECTRONIC STUDIES - CRYSTAL AND MOLECULAR-STRUCTURE OF [OS(C5ME5)2].+[BF4]-

DECAMETHYLOSMOCENE AND DECAMETHYLOSMOCENIUM - UV AND X-RAY PHOTOELECTRON, MAGNETIC, AND ELECTRONIC STUDIES - CRYSTAL AND MOLECULAR-STRUCTURE OF [OS(C5ME5)2].+[BF4]-

The complex [Os(C5Me5)2]•+[BF 4]- has been synthesized from Os(C5Me5)2 by oxidation with AgBF4. Os(C5Me5)2 exhibits a reversible one-electron oxidation at +0.27 vs SCE by cyclic voltammetry. Solid-state 13C CPMAS NMR experiments show an axial powder symmetry indicating fast ring rotation at room tem...

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Bibliographic Details
Main Authors:	Ohare, D, Green, J, Chadwick, T, Miller, J
Format:	Journal article
Language:	English
Published:	1988

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