DECAMETHYLOSMOCENE AND DECAMETHYLOSMOCENIUM - UV AND X-RAY PHOTOELECTRON, MAGNETIC, AND ELECTRONIC STUDIES - CRYSTAL AND MOLECULAR-STRUCTURE OF [OS(C5ME5)2].+[BF4]-
The complex [Os(C5Me5)2]•+[BF 4]- has been synthesized from Os(C5Me5)2 by oxidation with AgBF4. Os(C5Me5)2 exhibits a reversible one-electron oxidation at +0.27 vs SCE by cyclic voltammetry. Solid-state 13C CPMAS NMR experiments show an axial powder symmetry indicating fast ring rotation at room tem...
| Príomhchruthaitheoirí: | , , , |
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| Formáid: | Journal article |
| Teanga: | English |
| Foilsithe / Cruthaithe: |
1988
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