New catalytic strategies for the enantioselective synthesis of stereogenic-at-phosphorus(V) compounds
A 2nd-generation enantioselective catalytic desymmetrisation for direct access to enantioenriched P(V) stereocentres is described. Through use of a prochiral P(V) electrophile containing two thiazolidinone leaving groups and harnessing a bifunctional iminophosphorane (BIMP) superbase catalyst, this...
| Auteur principal: | |
|---|---|
| Autres auteurs: | |
| Format: | Thèse |
| Langue: | English |
| Publié: |
2022
|
| Sujets: |