New catalytic strategies for the enantioselective synthesis of stereogenic-at-phosphorus(V) compounds

New catalytic strategies for the enantioselective synthesis of stereogenic-at-phosphorus(V) compounds

A 2nd-generation enantioselective catalytic desymmetrisation for direct access to enantioenriched P(V) stereocentres is described. Through use of a prochiral P(V) electrophile containing two thiazolidinone leaving groups and harnessing a bifunctional iminophosphorane (BIMP) superbase catalyst, this...

Полное описание

Библиографические подробности
Главный автор:	Marsh, TGF
Другие авторы:	Dixon, D
Формат:	Диссертация
Язык:	English
Опубликовано:	2022
Предметы:	organic chemistry

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