New catalytic strategies for the enantioselective synthesis of stereogenic-at-phosphorus(V) compounds
A 2nd-generation enantioselective catalytic desymmetrisation for direct access to enantioenriched P(V) stereocentres is described. Through use of a prochiral P(V) electrophile containing two thiazolidinone leaving groups and harnessing a bifunctional iminophosphorane (BIMP) superbase catalyst, this...
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| 格式: | Thesis |
| 語言: | English |
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2022
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