CrCpTp: a high-spin Cr(II) sandwich complex with a large structural distortion.
CrCpTp was synthesized from the reaction of [CrCpCl](2) and KTp. Magnetic measurements indicate it to have a high-spin (S = 2) electronic configuration from 5 to 300 K. A single-crystal X-ray study reveals bond lengths typical for a high-spin configuration and a pronounced Jahn-Teller distortion. Th...
| Main Authors: | , , |
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| 格式: | Journal article |
| 语言: | English |
| 出版: |
2002
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