Potassium (de‐)insertion processes in Prussian blue particles: ensemble versus single nanoparticle behaviour
Potassium (de-)insertion from Prussian Blue (PB) is investigated at the single and multi-particle scale. The electrochemical behaviour is found to differ between the two measurement types. At the single particle level oxidation of the PB nanoparticles with concomitant K+ deinsertion occurs more read...
| Asıl Yazarlar: | , , , |
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| Materyal Türü: | Journal article |
| Baskı/Yayın Bilgisi: |
Wiley
2017
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| _version_ | 1826286323851329536 |
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| author | Zampardi, G Sokolov, S Batchelor-McAuley, C Compton, R |
| author_facet | Zampardi, G Sokolov, S Batchelor-McAuley, C Compton, R |
| author_sort | Zampardi, G |
| collection | OXFORD |
| description | Potassium (de-)insertion from Prussian Blue (PB) is investigated at the single and multi-particle scale. The electrochemical behaviour is found to differ between the two measurement types. At the single particle level oxidation of the PB nanoparticles with concomitant K+ deinsertion occurs more readily than the associated reduction, relating to K+ insertion. In contrast, the cyclic voltammetry of PB in a composite electrode containing conductive additives and polymeric binder suggests the opposite behaviour. Implications for assessing battery materials are discussed. |
| first_indexed | 2024-03-07T01:42:04Z |
| format | Journal article |
| id | oxford-uuid:9736deca-c6c3-4b02-bd4a-cfe6f5adc83b |
| institution | University of Oxford |
| last_indexed | 2024-03-07T01:42:04Z |
| publishDate | 2017 |
| publisher | Wiley |
| record_format | dspace |
| spelling | oxford-uuid:9736deca-c6c3-4b02-bd4a-cfe6f5adc83b2022-03-26T23:57:57ZPotassium (de‐)insertion processes in Prussian blue particles: ensemble versus single nanoparticle behaviourJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:9736deca-c6c3-4b02-bd4a-cfe6f5adc83bSymplectic Elements at OxfordWiley2017Zampardi, GSokolov, SBatchelor-McAuley, CCompton, RPotassium (de-)insertion from Prussian Blue (PB) is investigated at the single and multi-particle scale. The electrochemical behaviour is found to differ between the two measurement types. At the single particle level oxidation of the PB nanoparticles with concomitant K+ deinsertion occurs more readily than the associated reduction, relating to K+ insertion. In contrast, the cyclic voltammetry of PB in a composite electrode containing conductive additives and polymeric binder suggests the opposite behaviour. Implications for assessing battery materials are discussed. |
| spellingShingle | Zampardi, G Sokolov, S Batchelor-McAuley, C Compton, R Potassium (de‐)insertion processes in Prussian blue particles: ensemble versus single nanoparticle behaviour |
| title | Potassium (de‐)insertion processes in Prussian blue particles: ensemble versus single nanoparticle behaviour |
| title_full | Potassium (de‐)insertion processes in Prussian blue particles: ensemble versus single nanoparticle behaviour |
| title_fullStr | Potassium (de‐)insertion processes in Prussian blue particles: ensemble versus single nanoparticle behaviour |
| title_full_unstemmed | Potassium (de‐)insertion processes in Prussian blue particles: ensemble versus single nanoparticle behaviour |
| title_short | Potassium (de‐)insertion processes in Prussian blue particles: ensemble versus single nanoparticle behaviour |
| title_sort | potassium de insertion processes in prussian blue particles ensemble versus single nanoparticle behaviour |
| work_keys_str_mv | AT zampardig potassiumdeinsertionprocessesinprussianblueparticlesensembleversussinglenanoparticlebehaviour AT sokolovs potassiumdeinsertionprocessesinprussianblueparticlesensembleversussinglenanoparticlebehaviour AT batchelormcauleyc potassiumdeinsertionprocessesinprussianblueparticlesensembleversussinglenanoparticlebehaviour AT comptonr potassiumdeinsertionprocessesinprussianblueparticlesensembleversussinglenanoparticlebehaviour |