Directed dihydroxylation of cyclic allylic alcohols and trichloroacetamides using OsO4/TMEDA.
The oxidation of a range of cyclic allylic alcohols and amides with OsO4/TMEDA is presented. Under these conditions, hydrogen bonding control leads to the (contrasteric) formation of the syn isomer in almost every example that was examined. Evidence for the bidentate binding of TMEDA to OsO4 is pres...
Váldodahkkit: | , , , , , , , |
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Materiálatiipa: | Journal article |
Giella: | English |
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2002
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author | Donohoe, T Blades, K Moore, P Waring, M Winter, J Helliwell, M Newcombe, N Stemp, G |
author_facet | Donohoe, T Blades, K Moore, P Waring, M Winter, J Helliwell, M Newcombe, N Stemp, G |
author_sort | Donohoe, T |
collection | OXFORD |
description | The oxidation of a range of cyclic allylic alcohols and amides with OsO4/TMEDA is presented. Under these conditions, hydrogen bonding control leads to the (contrasteric) formation of the syn isomer in almost every example that was examined. Evidence for the bidentate binding of TMEDA to OsO4 is presented and a plausible mechanism described. |
first_indexed | 2024-03-07T01:42:16Z |
format | Journal article |
id | oxford-uuid:97475e7c-f91f-4c24-85b2-fa470c24f60b |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-07T01:42:16Z |
publishDate | 2002 |
record_format | dspace |
spelling | oxford-uuid:97475e7c-f91f-4c24-85b2-fa470c24f60b2022-03-26T23:58:30ZDirected dihydroxylation of cyclic allylic alcohols and trichloroacetamides using OsO4/TMEDA.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:97475e7c-f91f-4c24-85b2-fa470c24f60bEnglishSymplectic Elements at Oxford2002Donohoe, TBlades, KMoore, PWaring, MWinter, JHelliwell, MNewcombe, NStemp, GThe oxidation of a range of cyclic allylic alcohols and amides with OsO4/TMEDA is presented. Under these conditions, hydrogen bonding control leads to the (contrasteric) formation of the syn isomer in almost every example that was examined. Evidence for the bidentate binding of TMEDA to OsO4 is presented and a plausible mechanism described. |
spellingShingle | Donohoe, T Blades, K Moore, P Waring, M Winter, J Helliwell, M Newcombe, N Stemp, G Directed dihydroxylation of cyclic allylic alcohols and trichloroacetamides using OsO4/TMEDA. |
title | Directed dihydroxylation of cyclic allylic alcohols and trichloroacetamides using OsO4/TMEDA. |
title_full | Directed dihydroxylation of cyclic allylic alcohols and trichloroacetamides using OsO4/TMEDA. |
title_fullStr | Directed dihydroxylation of cyclic allylic alcohols and trichloroacetamides using OsO4/TMEDA. |
title_full_unstemmed | Directed dihydroxylation of cyclic allylic alcohols and trichloroacetamides using OsO4/TMEDA. |
title_short | Directed dihydroxylation of cyclic allylic alcohols and trichloroacetamides using OsO4/TMEDA. |
title_sort | directed dihydroxylation of cyclic allylic alcohols and trichloroacetamides using oso4 tmeda |
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