Directed dihydroxylation of cyclic allylic alcohols and trichloroacetamides using OsO4/TMEDA.
The oxidation of a range of cyclic allylic alcohols and amides with OsO4/TMEDA is presented. Under these conditions, hydrogen bonding control leads to the (contrasteric) formation of the syn isomer in almost every example that was examined. Evidence for the bidentate binding of TMEDA to OsO4 is pres...
Glavni autori: | Donohoe, T, Blades, K, Moore, P, Waring, M, Winter, J, Helliwell, M, Newcombe, N, Stemp, G |
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Format: | Journal article |
Jezik: | English |
Izdano: |
2002
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Slični predmeti
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Directed dihydroxylation of allylic trichloroacetamides
od: Donohoe, T, i dr.
Izdano: (1999) -
A syn selective dihydroxylation of cyclic allylic trichloroacetamides using catalytic osmium tetroxide
od: Blades, K, i dr.
Izdano: (2000) -
Homoallylic alcohols and trichloroacetamides as hydrogen bond donors for directed dihydroxylation
od: Donohoe, T, i dr.
Izdano: (2001) -
The directed dihydroxylation of allylic alcohols
od: Donohoe, T, i dr.
Izdano: (1997) -
Syn-syn dihydroxylation of allylic amides.
od: Winter, J, i dr.
Izdano: (2000)