Diamond electrochemistry at the nanoscale: A review

Diamond electrochemistry using planar macroscopic diamond films has been widely investigated. Due to the non-uniform doping in diamond, boundary effects, and the varied ratios of graphite to diamond, such systems only provide averaged electrochemical signals over the full electrode. To clarify elect...

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Main Authors: Yang, N, Foord, J, Jiang, X
Format: Journal article
Published: Elsevier 2015
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author Yang, N
Foord, J
Jiang, X
author_facet Yang, N
Foord, J
Jiang, X
author_sort Yang, N
collection OXFORD
description Diamond electrochemistry using planar macroscopic diamond films has been widely investigated. Due to the non-uniform doping in diamond, boundary effects, and the varied ratios of graphite to diamond, such systems only provide averaged electrochemical signals over the full electrode. To clarify electrical and electrochemical properties of diamond at the nanoscale, the use of diamond nanostructures (e.g., nanotextures, nanowires, networks, porous film, nanoelectrodes, etc.) and particles (e.g., undoped nanoparticles, boron-doped particles), is highly important. In this review, recent progress and achievements concerning diamond nanoelectrochemistry are considered. After a brief introduction of synthetic strategies to form diamond nanostructures and particles, their electrochemical properties in the presence and absence of redox probes are shown, followed by their use in electroanalysis (e.g., electrochemical, biochemical sensing, etc), electrochemical energy storage (e.g., electrochemical capacitors, batteries, etc.), electrocatalysis, and related applications. Topical problems and future of diamond nanoelectrochemistry are discussed.
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spelling oxford-uuid:986633c4-e60a-4470-b246-fa90e1bc437e2022-03-27T00:06:44ZDiamond electrochemistry at the nanoscale: A reviewJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:986633c4-e60a-4470-b246-fa90e1bc437eSymplectic Elements at OxfordElsevier2015Yang, NFoord, JJiang, XDiamond electrochemistry using planar macroscopic diamond films has been widely investigated. Due to the non-uniform doping in diamond, boundary effects, and the varied ratios of graphite to diamond, such systems only provide averaged electrochemical signals over the full electrode. To clarify electrical and electrochemical properties of diamond at the nanoscale, the use of diamond nanostructures (e.g., nanotextures, nanowires, networks, porous film, nanoelectrodes, etc.) and particles (e.g., undoped nanoparticles, boron-doped particles), is highly important. In this review, recent progress and achievements concerning diamond nanoelectrochemistry are considered. After a brief introduction of synthetic strategies to form diamond nanostructures and particles, their electrochemical properties in the presence and absence of redox probes are shown, followed by their use in electroanalysis (e.g., electrochemical, biochemical sensing, etc), electrochemical energy storage (e.g., electrochemical capacitors, batteries, etc.), electrocatalysis, and related applications. Topical problems and future of diamond nanoelectrochemistry are discussed.
spellingShingle Yang, N
Foord, J
Jiang, X
Diamond electrochemistry at the nanoscale: A review
title Diamond electrochemistry at the nanoscale: A review
title_full Diamond electrochemistry at the nanoscale: A review
title_fullStr Diamond electrochemistry at the nanoscale: A review
title_full_unstemmed Diamond electrochemistry at the nanoscale: A review
title_short Diamond electrochemistry at the nanoscale: A review
title_sort diamond electrochemistry at the nanoscale a review
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AT foordj diamondelectrochemistryatthenanoscaleareview
AT jiangx diamondelectrochemistryatthenanoscaleareview