Enantioselective rearrangement of exo-norbornene oxide to nortricyclanol
The enantioselective α-deprotonation-rearrangement of exo-norbornene oxide 1 to (-)-nortricyclanol 2 in up to 52% ee using a nonracemic lithium amide, or an organolithium in the presence of (-)-sparteine, is described.
Hoofdauteurs: | , |
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Formaat: | Journal article |
Taal: | English |
Gepubliceerd in: |
1996
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Samenvatting: | The enantioselective α-deprotonation-rearrangement of exo-norbornene oxide 1 to (-)-nortricyclanol 2 in up to 52% ee using a nonracemic lithium amide, or an organolithium in the presence of (-)-sparteine, is described. |
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