Enantioselective rearrangement of exo-norbornene oxide to nortricyclanol

The enantioselective α-deprotonation-rearrangement of exo-norbornene oxide 1 to (-)-nortricyclanol 2 in up to 52% ee using a nonracemic lithium amide, or an organolithium in the presence of (-)-sparteine, is described.

Номзүйн дэлгэрэнгүй
Үндсэн зохиолчид: Hodgson, D, Wisedale, R
Формат: Journal article
Хэл сонгох:English
Хэвлэсэн: 1996