Review—"Knees" in lithium-ion battery aging trajectories
Lithium-ion batteries can last many years but sometimes exhibit rapid, nonlinear degradation that severely limits battery lifetime. In this work, we review prior work on "knees" in lithium-ion battery aging trajectories. We first review definitions for knees and three classes of "inte...
| Hoofdauteurs: | , , , , , , , , , , , , , , , , |
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| Formaat: | Journal article |
| Taal: | English |
| Gepubliceerd in: |
IOP Publishing
2022
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| _version_ | 1826308072035844096 |
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| author | Attia, PM Bills, AA Brosa Planella, F Dechent, P dos Reis, G Dubarry, M Gasper, P Gilchrist, R Greenbank, S Howey, D Liu, O Khoo, E Preger, Y Soni, A Sripad, S Stefanopoulou, A Sulzer, V |
| author_facet | Attia, PM Bills, AA Brosa Planella, F Dechent, P dos Reis, G Dubarry, M Gasper, P Gilchrist, R Greenbank, S Howey, D Liu, O Khoo, E Preger, Y Soni, A Sripad, S Stefanopoulou, A Sulzer, V |
| author_sort | Attia, PM |
| collection | OXFORD |
| description | Lithium-ion batteries can last many years but sometimes exhibit rapid, nonlinear degradation that severely limits battery lifetime. In this work, we review prior work on "knees" in lithium-ion battery aging trajectories. We first review definitions for knees and three classes of "internal state trajectories" (termed snowball, hidden, and threshold trajectories) that can cause a knee. We then discuss six knee "pathways", including lithium plating, electrode saturation, resistance growth, electrolyte and additive depletion, percolation-limited connectivity, and mechanical deformation—some of which have internal state trajectories with signals that are electrochemically undetectable. We also identify key design and usage sensitivities for knees. Finally, we discuss challenges and opportunities for knee modeling and prediction. Our findings illustrate the complexity and subtlety of lithium-ion battery degradation and can aid both academic and industrial efforts to improve battery lifetime. |
| first_indexed | 2024-03-07T07:14:05Z |
| format | Journal article |
| id | oxford-uuid:98d1d797-1600-45ba-9475-a1406a21f221 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T07:14:05Z |
| publishDate | 2022 |
| publisher | IOP Publishing |
| record_format | dspace |
| spelling | oxford-uuid:98d1d797-1600-45ba-9475-a1406a21f2212022-07-14T09:36:31ZReview—"Knees" in lithium-ion battery aging trajectoriesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:98d1d797-1600-45ba-9475-a1406a21f221EnglishSymplectic ElementsIOP Publishing2022Attia, PMBills, AABrosa Planella, FDechent, Pdos Reis, GDubarry, MGasper, PGilchrist, RGreenbank, SHowey, DLiu, OKhoo, EPreger, YSoni, ASripad, SStefanopoulou, ASulzer, VLithium-ion batteries can last many years but sometimes exhibit rapid, nonlinear degradation that severely limits battery lifetime. In this work, we review prior work on "knees" in lithium-ion battery aging trajectories. We first review definitions for knees and three classes of "internal state trajectories" (termed snowball, hidden, and threshold trajectories) that can cause a knee. We then discuss six knee "pathways", including lithium plating, electrode saturation, resistance growth, electrolyte and additive depletion, percolation-limited connectivity, and mechanical deformation—some of which have internal state trajectories with signals that are electrochemically undetectable. We also identify key design and usage sensitivities for knees. Finally, we discuss challenges and opportunities for knee modeling and prediction. Our findings illustrate the complexity and subtlety of lithium-ion battery degradation and can aid both academic and industrial efforts to improve battery lifetime. |
| spellingShingle | Attia, PM Bills, AA Brosa Planella, F Dechent, P dos Reis, G Dubarry, M Gasper, P Gilchrist, R Greenbank, S Howey, D Liu, O Khoo, E Preger, Y Soni, A Sripad, S Stefanopoulou, A Sulzer, V Review—"Knees" in lithium-ion battery aging trajectories |
| title | Review—"Knees" in lithium-ion battery aging trajectories |
| title_full | Review—"Knees" in lithium-ion battery aging trajectories |
| title_fullStr | Review—"Knees" in lithium-ion battery aging trajectories |
| title_full_unstemmed | Review—"Knees" in lithium-ion battery aging trajectories |
| title_short | Review—"Knees" in lithium-ion battery aging trajectories |
| title_sort | review knees in lithium ion battery aging trajectories |
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