Prussian blue analogs as battery materials
Context & Scale: In this work, we offer our perspective on a class of compounds known as Prussian blue analogs, a group of versatile cyano-coordination polymers. Originally commercialized in the dye industry, they have more recently been used in diverse energy technologies including energy s...
| Hlavní autoři: | , , , |
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| Médium: | Journal article |
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Cell Press
2018
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| _version_ | 1826286688492584960 |
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| author | Hurlbutt, K Wheeler, S Capone, I Pasta, M |
| author_facet | Hurlbutt, K Wheeler, S Capone, I Pasta, M |
| author_sort | Hurlbutt, K |
| collection | OXFORD |
| description | Context & Scale: In this work, we offer our perspective on a class of compounds known as Prussian blue analogs, a group of versatile cyano-coordination polymers. Originally commercialized in the dye industry, they have more recently been used in diverse energy technologies including energy storage, electrocatalysis, and thermal power generation. We address their role as components of the next generation of batteries with improved cycle life and power capability. Through a review of achievements from early electrochemical experiments to crystallographic breakthroughs to development of state-of-the-art electrodes, we outline how control over the crystal structure allows these materials' electrochemistry to be tuned for diverse uses. Despite recent advances, there remain conspicuous and fundamental questions about the structure-electrochemistry relationship that we identify. We adumbrate investigations using density functional theory calculations, synchrotron X-ray techniques, electrochemical tests, and technoeconomic analyses to answer these questions. |
| first_indexed | 2024-03-07T01:47:27Z |
| format | Journal article |
| id | oxford-uuid:98ea6929-f24f-44f7-968b-b9f260bc727a |
| institution | University of Oxford |
| last_indexed | 2024-03-07T01:47:27Z |
| publishDate | 2018 |
| publisher | Cell Press |
| record_format | dspace |
| spelling | oxford-uuid:98ea6929-f24f-44f7-968b-b9f260bc727a2022-03-27T00:10:30ZPrussian blue analogs as battery materialsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:98ea6929-f24f-44f7-968b-b9f260bc727aSymplectic Elements at OxfordCell Press2018Hurlbutt, KWheeler, SCapone, IPasta, MContext & Scale: In this work, we offer our perspective on a class of compounds known as Prussian blue analogs, a group of versatile cyano-coordination polymers. Originally commercialized in the dye industry, they have more recently been used in diverse energy technologies including energy storage, electrocatalysis, and thermal power generation. We address their role as components of the next generation of batteries with improved cycle life and power capability. Through a review of achievements from early electrochemical experiments to crystallographic breakthroughs to development of state-of-the-art electrodes, we outline how control over the crystal structure allows these materials' electrochemistry to be tuned for diverse uses. Despite recent advances, there remain conspicuous and fundamental questions about the structure-electrochemistry relationship that we identify. We adumbrate investigations using density functional theory calculations, synchrotron X-ray techniques, electrochemical tests, and technoeconomic analyses to answer these questions. |
| spellingShingle | Hurlbutt, K Wheeler, S Capone, I Pasta, M Prussian blue analogs as battery materials |
| title | Prussian blue analogs as battery materials |
| title_full | Prussian blue analogs as battery materials |
| title_fullStr | Prussian blue analogs as battery materials |
| title_full_unstemmed | Prussian blue analogs as battery materials |
| title_short | Prussian blue analogs as battery materials |
| title_sort | prussian blue analogs as battery materials |
| work_keys_str_mv | AT hurlbuttk prussianblueanalogsasbatterymaterials AT wheelers prussianblueanalogsasbatterymaterials AT caponei prussianblueanalogsasbatterymaterials AT pastam prussianblueanalogsasbatterymaterials |