Discovery and evaluation of highly active imidotitanium ethylene polymerisation catalysts using high throughput catalyst screening.

A family of ca. 50 imidotitanium precatalysts [Ti(NR)(Me(3)[9]aneN(3))Cl(2)](R = alkyl or aryl; Me(3)[9]aneN(3)= 1,4,7-trimethyltriazacyclononane) were prepared in good yields using semi-automated procedures; high-throughput screening techniques identified seven highly active ethylene polymerisation...

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Главные авторы: Adams, N, Arts, H, Bolton, P, Cowell, D, Dubberley, SR, Friederichs, N, Grant, C, Kranenburg, M, Sealey, A, Wang, B, Wilson, P, Cowley, A, Mountford, P, Schröder, M
Формат: Journal article
Язык:English
Опубликовано: 2004
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author Adams, N
Arts, H
Bolton, P
Cowell, D
Dubberley, SR
Friederichs, N
Grant, C
Kranenburg, M
Sealey, A
Wang, B
Wilson, P
Cowley, A
Mountford, P
Schröder, M
author_facet Adams, N
Arts, H
Bolton, P
Cowell, D
Dubberley, SR
Friederichs, N
Grant, C
Kranenburg, M
Sealey, A
Wang, B
Wilson, P
Cowley, A
Mountford, P
Schröder, M
author_sort Adams, N
collection OXFORD
description A family of ca. 50 imidotitanium precatalysts [Ti(NR)(Me(3)[9]aneN(3))Cl(2)](R = alkyl or aryl; Me(3)[9]aneN(3)= 1,4,7-trimethyltriazacyclononane) were prepared in good yields using semi-automated procedures; high-throughput screening techniques identified seven highly active ethylene polymerisation precatalysts with activities in the range ca. 3 400 to 10 000 kg(PE) mol(-1) h(-1) bar(-1).
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spelling oxford-uuid:98fdce42-2869-41d7-a021-2669d02824d32022-03-27T00:11:09ZDiscovery and evaluation of highly active imidotitanium ethylene polymerisation catalysts using high throughput catalyst screening.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:98fdce42-2869-41d7-a021-2669d02824d3EnglishSymplectic Elements at Oxford2004Adams, NArts, HBolton, PCowell, DDubberley, SRFriederichs, NGrant, CKranenburg, MSealey, AWang, BWilson, PCowley, AMountford, PSchröder, MA family of ca. 50 imidotitanium precatalysts [Ti(NR)(Me(3)[9]aneN(3))Cl(2)](R = alkyl or aryl; Me(3)[9]aneN(3)= 1,4,7-trimethyltriazacyclononane) were prepared in good yields using semi-automated procedures; high-throughput screening techniques identified seven highly active ethylene polymerisation precatalysts with activities in the range ca. 3 400 to 10 000 kg(PE) mol(-1) h(-1) bar(-1).
spellingShingle Adams, N
Arts, H
Bolton, P
Cowell, D
Dubberley, SR
Friederichs, N
Grant, C
Kranenburg, M
Sealey, A
Wang, B
Wilson, P
Cowley, A
Mountford, P
Schröder, M
Discovery and evaluation of highly active imidotitanium ethylene polymerisation catalysts using high throughput catalyst screening.
title Discovery and evaluation of highly active imidotitanium ethylene polymerisation catalysts using high throughput catalyst screening.
title_full Discovery and evaluation of highly active imidotitanium ethylene polymerisation catalysts using high throughput catalyst screening.
title_fullStr Discovery and evaluation of highly active imidotitanium ethylene polymerisation catalysts using high throughput catalyst screening.
title_full_unstemmed Discovery and evaluation of highly active imidotitanium ethylene polymerisation catalysts using high throughput catalyst screening.
title_short Discovery and evaluation of highly active imidotitanium ethylene polymerisation catalysts using high throughput catalyst screening.
title_sort discovery and evaluation of highly active imidotitanium ethylene polymerisation catalysts using high throughput catalyst screening
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