Discovery and evaluation of highly active imidotitanium ethylene polymerisation catalysts using high throughput catalyst screening.
A family of ca. 50 imidotitanium precatalysts [Ti(NR)(Me(3)[9]aneN(3))Cl(2)](R = alkyl or aryl; Me(3)[9]aneN(3)= 1,4,7-trimethyltriazacyclononane) were prepared in good yields using semi-automated procedures; high-throughput screening techniques identified seven highly active ethylene polymerisation...
Main Authors: | Adams, N, Arts, H, Bolton, P, Cowell, D, Dubberley, SR, Friederichs, N, Grant, C, Kranenburg, M, Sealey, A, Wang, B, Wilson, P, Cowley, A, Mountford, P, Schröder, M |
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Format: | Journal article |
Jezik: | English |
Izdano: |
2004
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