MAGNETISM, SUPERCONDUCTIVITY, AND THE METAL NONMETAL TRANSITION IN THE SPINEL LIAL-3+XTI2-XO4, LICR-3+XTI2-XO4

In the LiMxTi2-xO4 (M = Cr3+, Al3+) spinel solid solution systems, the M3+ cations substitute at the octahedral sites and thus directly interact with the titanium 3d conduction electrons. The effect is dramatically illustrated in the chromium series where superconductivity is supressed completely at...

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Päätekijät: Lambert, P, Edwards, P, Harrison, M
Aineistotyyppi: Journal article
Kieli:English
Julkaistu: 1990
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author Lambert, P
Edwards, P
Harrison, M
author_facet Lambert, P
Edwards, P
Harrison, M
author_sort Lambert, P
collection OXFORD
description In the LiMxTi2-xO4 (M = Cr3+, Al3+) spinel solid solution systems, the M3+ cations substitute at the octahedral sites and thus directly interact with the titanium 3d conduction electrons. The effect is dramatically illustrated in the chromium series where superconductivity is supressed completely at 2.5% Cr3+ substitution by a magnetic impurity effect. Infrared transmission measurements indicate a metal-nonmetal transition (MNMT) in LiCrxTi2-xO4 at 0.33 < x < 0.40. In the aluminum series, the superconducting transition temperature Tc persists at a high value (> 6 K) to x = 0.33, where a MNMT is proposed. Percolation, disproportionation, and conduction electron concentration are briefly discussed as possible contributing mechanisms for the MNMT in the cation-substituted LiMxTi2-xO4 (M = Li+, Al3+, Cr3+) system. © 1990.
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spelling oxford-uuid:9944948f-b6db-4a6e-b3f4-450599fca2b82022-03-27T00:13:08ZMAGNETISM, SUPERCONDUCTIVITY, AND THE METAL NONMETAL TRANSITION IN THE SPINEL LIAL-3+XTI2-XO4, LICR-3+XTI2-XO4Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:9944948f-b6db-4a6e-b3f4-450599fca2b8EnglishSymplectic Elements at Oxford1990Lambert, PEdwards, PHarrison, MIn the LiMxTi2-xO4 (M = Cr3+, Al3+) spinel solid solution systems, the M3+ cations substitute at the octahedral sites and thus directly interact with the titanium 3d conduction electrons. The effect is dramatically illustrated in the chromium series where superconductivity is supressed completely at 2.5% Cr3+ substitution by a magnetic impurity effect. Infrared transmission measurements indicate a metal-nonmetal transition (MNMT) in LiCrxTi2-xO4 at 0.33 < x < 0.40. In the aluminum series, the superconducting transition temperature Tc persists at a high value (> 6 K) to x = 0.33, where a MNMT is proposed. Percolation, disproportionation, and conduction electron concentration are briefly discussed as possible contributing mechanisms for the MNMT in the cation-substituted LiMxTi2-xO4 (M = Li+, Al3+, Cr3+) system. © 1990.
spellingShingle Lambert, P
Edwards, P
Harrison, M
MAGNETISM, SUPERCONDUCTIVITY, AND THE METAL NONMETAL TRANSITION IN THE SPINEL LIAL-3+XTI2-XO4, LICR-3+XTI2-XO4
title MAGNETISM, SUPERCONDUCTIVITY, AND THE METAL NONMETAL TRANSITION IN THE SPINEL LIAL-3+XTI2-XO4, LICR-3+XTI2-XO4
title_full MAGNETISM, SUPERCONDUCTIVITY, AND THE METAL NONMETAL TRANSITION IN THE SPINEL LIAL-3+XTI2-XO4, LICR-3+XTI2-XO4
title_fullStr MAGNETISM, SUPERCONDUCTIVITY, AND THE METAL NONMETAL TRANSITION IN THE SPINEL LIAL-3+XTI2-XO4, LICR-3+XTI2-XO4
title_full_unstemmed MAGNETISM, SUPERCONDUCTIVITY, AND THE METAL NONMETAL TRANSITION IN THE SPINEL LIAL-3+XTI2-XO4, LICR-3+XTI2-XO4
title_short MAGNETISM, SUPERCONDUCTIVITY, AND THE METAL NONMETAL TRANSITION IN THE SPINEL LIAL-3+XTI2-XO4, LICR-3+XTI2-XO4
title_sort magnetism superconductivity and the metal nonmetal transition in the spinel lial 3 xti2 xo4 licr 3 xti2 xo4
work_keys_str_mv AT lambertp magnetismsuperconductivityandthemetalnonmetaltransitioninthespinellial3xti2xo4licr3xti2xo4
AT edwardsp magnetismsuperconductivityandthemetalnonmetaltransitioninthespinellial3xti2xo4licr3xti2xo4
AT harrisonm magnetismsuperconductivityandthemetalnonmetaltransitioninthespinellial3xti2xo4licr3xti2xo4