[Rh{NC5H3-2,6-((CH2PBu2)-Bu-t)(2)}(PCY3)][BAr4F]: A Latent Low-Coordinate Rhodium(I) PNP Pincer Compound

An expedient new route to the cationic [(PNPtBu)Rh(L)] + metal fragments (PNPtBu = κ3-NC 5H3-2,6-(CH2P tBu2) 2; L = CO, acetone, ethene, MeCN, N2) by the synthesis of, then substitution of PCy3 in, [(PNPtBu)Rh(PCy 3)][BArF4] is reported. This synthetic route also allows for the synthesis of the new...

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Main Authors: Chaplin, AB, Weller, A
Format: Journal article
Language:English
Published: 2011
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author Chaplin, AB
Weller, A
author_facet Chaplin, AB
Weller, A
author_sort Chaplin, AB
collection OXFORD
description An expedient new route to the cationic [(PNPtBu)Rh(L)] + metal fragments (PNPtBu = κ3-NC 5H3-2,6-(CH2P tBu2) 2; L = CO, acetone, ethene, MeCN, N2) by the synthesis of, then substitution of PCy3 in, [(PNPtBu)Rh(PCy 3)][BArF4] is reported. This synthetic route also allows for the synthesis of the new dihydrogen complex [(PNP tBu)Rh(H2)][BArF4]. [(PNP R)Rh(PCy3)][BArF4] (R= Ph, Cy, Mes) are also reported, in which the PCy3 ligand is more tightly bound to the metal center. © 2011 American Chemical Society.
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spelling oxford-uuid:9a010816-c17f-4871-ad8f-269bf21350952022-03-27T00:18:17Z[Rh{NC5H3-2,6-((CH2PBu2)-Bu-t)(2)}(PCY3)][BAr4F]: A Latent Low-Coordinate Rhodium(I) PNP Pincer CompoundJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:9a010816-c17f-4871-ad8f-269bf2135095EnglishSymplectic Elements at Oxford2011Chaplin, ABWeller, AAn expedient new route to the cationic [(PNPtBu)Rh(L)] + metal fragments (PNPtBu = κ3-NC 5H3-2,6-(CH2P tBu2) 2; L = CO, acetone, ethene, MeCN, N2) by the synthesis of, then substitution of PCy3 in, [(PNPtBu)Rh(PCy 3)][BArF4] is reported. This synthetic route also allows for the synthesis of the new dihydrogen complex [(PNP tBu)Rh(H2)][BArF4]. [(PNP R)Rh(PCy3)][BArF4] (R= Ph, Cy, Mes) are also reported, in which the PCy3 ligand is more tightly bound to the metal center. © 2011 American Chemical Society.
spellingShingle Chaplin, AB
Weller, A
[Rh{NC5H3-2,6-((CH2PBu2)-Bu-t)(2)}(PCY3)][BAr4F]: A Latent Low-Coordinate Rhodium(I) PNP Pincer Compound
title [Rh{NC5H3-2,6-((CH2PBu2)-Bu-t)(2)}(PCY3)][BAr4F]: A Latent Low-Coordinate Rhodium(I) PNP Pincer Compound
title_full [Rh{NC5H3-2,6-((CH2PBu2)-Bu-t)(2)}(PCY3)][BAr4F]: A Latent Low-Coordinate Rhodium(I) PNP Pincer Compound
title_fullStr [Rh{NC5H3-2,6-((CH2PBu2)-Bu-t)(2)}(PCY3)][BAr4F]: A Latent Low-Coordinate Rhodium(I) PNP Pincer Compound
title_full_unstemmed [Rh{NC5H3-2,6-((CH2PBu2)-Bu-t)(2)}(PCY3)][BAr4F]: A Latent Low-Coordinate Rhodium(I) PNP Pincer Compound
title_short [Rh{NC5H3-2,6-((CH2PBu2)-Bu-t)(2)}(PCY3)][BAr4F]: A Latent Low-Coordinate Rhodium(I) PNP Pincer Compound
title_sort rh nc5h3 2 6 ch2pbu2 bu t 2 pcy3 bar4f a latent low coordinate rhodium i pnp pincer compound
work_keys_str_mv AT chaplinab rhnc5h326ch2pbu2but2pcy3bar4falatentlowcoordinaterhodiumipnppincercompound
AT wellera rhnc5h326ch2pbu2but2pcy3bar4falatentlowcoordinaterhodiumipnppincercompound