[Rh{NC5H3-2,6-((CH2PBu2)-Bu-t)(2)}(PCY3)][BAr4F]: A Latent Low-Coordinate Rhodium(I) PNP Pincer Compound
An expedient new route to the cationic [(PNPtBu)Rh(L)] + metal fragments (PNPtBu = κ3-NC 5H3-2,6-(CH2P tBu2) 2; L = CO, acetone, ethene, MeCN, N2) by the synthesis of, then substitution of PCy3 in, [(PNPtBu)Rh(PCy 3)][BArF4] is reported. This synthetic route also allows for the synthesis of the new...
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Format: | Journal article |
Language: | English |
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2011
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author | Chaplin, AB Weller, A |
author_facet | Chaplin, AB Weller, A |
author_sort | Chaplin, AB |
collection | OXFORD |
description | An expedient new route to the cationic [(PNPtBu)Rh(L)] + metal fragments (PNPtBu = κ3-NC 5H3-2,6-(CH2P tBu2) 2; L = CO, acetone, ethene, MeCN, N2) by the synthesis of, then substitution of PCy3 in, [(PNPtBu)Rh(PCy 3)][BArF4] is reported. This synthetic route also allows for the synthesis of the new dihydrogen complex [(PNP tBu)Rh(H2)][BArF4]. [(PNP R)Rh(PCy3)][BArF4] (R= Ph, Cy, Mes) are also reported, in which the PCy3 ligand is more tightly bound to the metal center. © 2011 American Chemical Society. |
first_indexed | 2024-03-07T01:50:44Z |
format | Journal article |
id | oxford-uuid:9a010816-c17f-4871-ad8f-269bf2135095 |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-07T01:50:44Z |
publishDate | 2011 |
record_format | dspace |
spelling | oxford-uuid:9a010816-c17f-4871-ad8f-269bf21350952022-03-27T00:18:17Z[Rh{NC5H3-2,6-((CH2PBu2)-Bu-t)(2)}(PCY3)][BAr4F]: A Latent Low-Coordinate Rhodium(I) PNP Pincer CompoundJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:9a010816-c17f-4871-ad8f-269bf2135095EnglishSymplectic Elements at Oxford2011Chaplin, ABWeller, AAn expedient new route to the cationic [(PNPtBu)Rh(L)] + metal fragments (PNPtBu = κ3-NC 5H3-2,6-(CH2P tBu2) 2; L = CO, acetone, ethene, MeCN, N2) by the synthesis of, then substitution of PCy3 in, [(PNPtBu)Rh(PCy 3)][BArF4] is reported. This synthetic route also allows for the synthesis of the new dihydrogen complex [(PNP tBu)Rh(H2)][BArF4]. [(PNP R)Rh(PCy3)][BArF4] (R= Ph, Cy, Mes) are also reported, in which the PCy3 ligand is more tightly bound to the metal center. © 2011 American Chemical Society. |
spellingShingle | Chaplin, AB Weller, A [Rh{NC5H3-2,6-((CH2PBu2)-Bu-t)(2)}(PCY3)][BAr4F]: A Latent Low-Coordinate Rhodium(I) PNP Pincer Compound |
title | [Rh{NC5H3-2,6-((CH2PBu2)-Bu-t)(2)}(PCY3)][BAr4F]: A Latent Low-Coordinate Rhodium(I) PNP Pincer Compound |
title_full | [Rh{NC5H3-2,6-((CH2PBu2)-Bu-t)(2)}(PCY3)][BAr4F]: A Latent Low-Coordinate Rhodium(I) PNP Pincer Compound |
title_fullStr | [Rh{NC5H3-2,6-((CH2PBu2)-Bu-t)(2)}(PCY3)][BAr4F]: A Latent Low-Coordinate Rhodium(I) PNP Pincer Compound |
title_full_unstemmed | [Rh{NC5H3-2,6-((CH2PBu2)-Bu-t)(2)}(PCY3)][BAr4F]: A Latent Low-Coordinate Rhodium(I) PNP Pincer Compound |
title_short | [Rh{NC5H3-2,6-((CH2PBu2)-Bu-t)(2)}(PCY3)][BAr4F]: A Latent Low-Coordinate Rhodium(I) PNP Pincer Compound |
title_sort | rh nc5h3 2 6 ch2pbu2 bu t 2 pcy3 bar4f a latent low coordinate rhodium i pnp pincer compound |
work_keys_str_mv | AT chaplinab rhnc5h326ch2pbu2but2pcy3bar4falatentlowcoordinaterhodiumipnppincercompound AT wellera rhnc5h326ch2pbu2but2pcy3bar4falatentlowcoordinaterhodiumipnppincercompound |