Lanthanide cation-templated synthesis of rotaxanes.

The first lanthanide cation-templated synthesis of an interlocked structure is demonstrated through an interpenetrated assembly between a pyridine N-oxide threading component coordinating to a lanthanide cation complexed within a macrocycle. Stoppering of the pseudo-rotaxane assembly allows for prep...

Полное описание

Библиографические подробности
Главные авторы: Zapata, F, Blackburn, O, Langton, M, Faulkner, S, Beer, P
Формат: Journal article
Язык:English
Опубликовано: 2013
Описание
Итог:The first lanthanide cation-templated synthesis of an interlocked structure is demonstrated through an interpenetrated assembly between a pyridine N-oxide threading component coordinating to a lanthanide cation complexed within a macrocycle. Stoppering of the pseudo-rotaxane assembly allows for preparation of the [2]rotaxane.