Lanthanide cation-templated synthesis of rotaxanes.

The first lanthanide cation-templated synthesis of an interlocked structure is demonstrated through an interpenetrated assembly between a pyridine N-oxide threading component coordinating to a lanthanide cation complexed within a macrocycle. Stoppering of the pseudo-rotaxane assembly allows for prep...

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Những tác giả chính: Zapata, F, Blackburn, O, Langton, M, Faulkner, S, Beer, P
Định dạng: Journal article
Ngôn ngữ:English
Được phát hành: 2013
Miêu tả
Tóm tắt:The first lanthanide cation-templated synthesis of an interlocked structure is demonstrated through an interpenetrated assembly between a pyridine N-oxide threading component coordinating to a lanthanide cation complexed within a macrocycle. Stoppering of the pseudo-rotaxane assembly allows for preparation of the [2]rotaxane.