Resonances in the O(P-3) plus HCl reaction due to van der Waals minima
The quantum calculations of the cumulative reaction probability (CRP) for the O(3P) + HCl→OH + Cl reaction were presented for a large range of total angular momentum. It was found that the potential energy surface (PES) contained Vander Waals minima in both the entrance and exit channel, which were...
| Hauptverfasser: | , , , |
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| Format: | Journal article |
| Sprache: | English |
| Veröffentlicht: |
2002
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| Zusammenfassung: | The quantum calculations of the cumulative reaction probability (CRP) for the O(3P) + HCl→OH + Cl reaction were presented for a large range of total angular momentum. It was found that the potential energy surface (PES) contained Vander Waals minima in both the entrance and exit channel, which were responsible for a number of resonances in the CRP in the tunneling region. The shift of the CRP with total angular momentum was also discussed. |
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