Metal-Metal Bonding in M(2)Cl(6)(H(2)PCH(2)PH(2))(2), M(2)Cl(6)(PH(3))(4), and M(2)Cl(10)(4-) (M = Cr, Mo, W) Edge-Shared Dimer Systems.

Density functional theory is used to determine the electronic structures, geometries, and periodic trends in metal-metal bonding in the homo- and heterobimetallic d(3)d(3) edge-shared systems M(2)Cl(10)(4-), M(2)Cl(6)(PH(3))(4), and M(2)Cl(6)(H(2)PCH(2)PH(2))(2) (M = Cr, Mo, W). The much shorter met...

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Manylion Llyfryddiaeth
Prif Awduron: Stranger, R, Lovell, T, McGrady, J
Fformat: Journal article
Iaith:English
Cyhoeddwyd: 1999