Reactions of titanium imides and hydrazides with boranes

We report the first reactions of titanium imido, alkylidene hydrazido and dimethylhydrazido compounds with the boranes H2BTex, 9-BBN, HBArF2 and HBPin (Tex = tert-hexyl; ArF = C6F5). Reactions of Cp*Ti{MeC(NiPr)2}(NTol) with H2BTex, 9-BBN or HBArF2 resulted in the hydride-bridged adducts Cp*Ti{MeC(N...

Ausführliche Beschreibung

Bibliographische Detailangaben
Hauptverfasser: Mellino, S, Stevenson, L, Clot, E, Mountford, P
Format: Journal article
Veröffentlicht: American Chemical Society 2017