Precise structure activity relationships in asymmetric catalysis using carbohydrate scaffolds to allow ready fine tuning: dialkylzinc-aldehyde additions.

The ready construction of 24 stereochemically and functionally diverse carbohydrate ligand structures from a core D-glucosamine scaffold has allowed the evaluation of broad ranging structure activity relationships in ligand accelerated zincate additions to aldehydes, with variations in deltadeltaG+/...

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Váldodahkkit: Emmerson, D, Villard, R, Mugnaini, C, Batsanov, A, Howard, J, Hems, W, Tooze, R, Davis, B
Materiálatiipa: Journal article
Giella:English
Almmustuhtton: 2003