Template-directed synthesis of a conjugated zinc porphyrin nanoball
We report the template-directed synthesis of a π-conjugated 14-porphyrin nanoball. This structure consists of two intersecting nanorings containing six and 10 porphyrin units. Fluorescence upconversion spectroscopy experiments demonstrate that electronic excitation delocalizes over the whole three-d...
| Main Authors: | , , , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
American Chemical Society
2018
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| _version_ | 1826287240579383296 |
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| author | Cremers, J Haver, R Rickhaus, M Gong, J Favereau, L Peeks, M Claridge, T Herz, L Anderson, H |
| author_facet | Cremers, J Haver, R Rickhaus, M Gong, J Favereau, L Peeks, M Claridge, T Herz, L Anderson, H |
| author_sort | Cremers, J |
| collection | OXFORD |
| description | We report the template-directed synthesis of a π-conjugated 14-porphyrin nanoball. This structure consists of two intersecting nanorings containing six and 10 porphyrin units. Fluorescence upconversion spectroscopy experiments demonstrate that electronic excitation delocalizes over the whole three-dimensional π system in less than 0.3 ps if the nanoball is bound to its templates or over 2 ps if the nanoball is empty. |
| first_indexed | 2024-03-07T01:55:41Z |
| format | Journal article |
| id | oxford-uuid:9b9f4aca-c8e2-4f3f-99be-c4332413930e |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T01:55:41Z |
| publishDate | 2018 |
| publisher | American Chemical Society |
| record_format | dspace |
| spelling | oxford-uuid:9b9f4aca-c8e2-4f3f-99be-c4332413930e2022-03-27T00:30:11ZTemplate-directed synthesis of a conjugated zinc porphyrin nanoballJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:9b9f4aca-c8e2-4f3f-99be-c4332413930eEnglishSymplectic Elements at OxfordAmerican Chemical Society2018Cremers, JHaver, RRickhaus, MGong, JFavereau, LPeeks, MClaridge, THerz, LAnderson, HWe report the template-directed synthesis of a π-conjugated 14-porphyrin nanoball. This structure consists of two intersecting nanorings containing six and 10 porphyrin units. Fluorescence upconversion spectroscopy experiments demonstrate that electronic excitation delocalizes over the whole three-dimensional π system in less than 0.3 ps if the nanoball is bound to its templates or over 2 ps if the nanoball is empty. |
| spellingShingle | Cremers, J Haver, R Rickhaus, M Gong, J Favereau, L Peeks, M Claridge, T Herz, L Anderson, H Template-directed synthesis of a conjugated zinc porphyrin nanoball |
| title | Template-directed synthesis of a conjugated zinc porphyrin nanoball |
| title_full | Template-directed synthesis of a conjugated zinc porphyrin nanoball |
| title_fullStr | Template-directed synthesis of a conjugated zinc porphyrin nanoball |
| title_full_unstemmed | Template-directed synthesis of a conjugated zinc porphyrin nanoball |
| title_short | Template-directed synthesis of a conjugated zinc porphyrin nanoball |
| title_sort | template directed synthesis of a conjugated zinc porphyrin nanoball |
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