Monitoring potassium metal electrodeposition from an ionic liquid using in situ electrochemical-X-ray photoelectron spectroscopy

The real time electrodeposition of potassium has been monitored for the first time in an ionic liquid using in situ electrodeposition-X-ray photoelectron spectroscopy (XPS). The ionic liquid used was N-butyl-N- methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ([C4mpyrr] [NTf2]), and electrodepo...

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Bibliographic Details
Main Authors: Wibowo, R, Aldous, L, Jacobs, R, Manan, N, Compton, R
Format: Journal article
Language:English
Published: 2011
Description
Summary:The real time electrodeposition of potassium has been monitored for the first time in an ionic liquid using in situ electrodeposition-X-ray photoelectron spectroscopy (XPS). The ionic liquid used was N-butyl-N- methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ([C4mpyrr] [NTf2]), and electrodeposition occurred at a nickel mesh electrode. Potassium electrochemistry was monitored at the ionic liquid-vacuum-electrode interface using a novel cell design. © 2011 Elsevier B.V. All rights reserved.